梯度增强异核相关光谱学。理论和实验方面

Jesus Ruiz-Cabello , Geerten W Vuister , Chrit T.W Moonen , Peter van Gelderen , Jack S Cohen , Peter C.M van Zijl
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引用次数: 137

摘要

对梯度增强异核相关光谱进行了详细的理论和实验处理。描述了多量子和单量子序列。除了与使用相位循环的传统实验进行比较外,还研究了不同梯度组合对异核维度中发生的伪影的影响。讨论了梯度性能和扩散对灵敏度的影响。分析了获得相敏光谱的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Gradient-enhanced heteronuclear correlation spectroscopy. Theory and experimental aspects

A detailed theoretical and experimental treatment is given for gradient-enhanced heteronuclear correlation spectroscopy. Both multiple-quantum and single-quantum sequences are described. In addition to a comparison with conventional experiments using phase cycling, the effects of different gradient combinations are examined with respect to artifacts occurring in the heteronuclear dimension. The influence of gradient performance and diffusion on sensitivity is discussed. Approaches to attain phase-sensitive spectra are also analyzed.

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