石墨烯:锂离子电池的化学和应用

Roshny Joy, Neethu T. M. Balakrishnan, A. Das, S. Shafeek, V. Thakur, K. Zaghib, Jabeen Fatima Manamkeri Jaffarali, M. V. Reddy, P. Raghavan
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引用次数: 9

摘要

在当今时代,碳的不同同素异形体已经被发现,石墨烯是其中之一,为许多研究突破做出了贡献。在过去的十年里,它一直被认为是研究和学术领域以及工业领域的一个有前途的候选人。它有许多有待探索的特性,如增强的比表面积和有益的导热性和导电性。石墨烯通过组织sp2杂化C的单键和双键交替排列成二维结构,提供扩展共轭结合六边形环结构形成蜂窝状结构。其珍贵的结构和突出的特性是现代工业对石墨烯依赖很大的主要原因,石墨烯主要应用于电子器件。目前,锂离子电池(LIBs)主要利用石墨烯作为阳极或阴极,并与聚合物结合使用,作为聚合物电解质。锂离子电池在商业化三十年后,以其更高的能量密度、更宽的工作电压、低自放电、优异的高温性能和更少的维护要求,在消费电子社会中仍然处于领先地位。在这篇综述中,我们旨在简要回顾石墨烯的统治地位及其在lib中的应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Graphene: Chemistry and Applications for Lithium-Ion Batteries
In the present era, different allotropes of carbon have been discovered, and graphene is the one among them that has contributed to many breakthroughs in research. It has been considered a promising candidate in the research and academic fields, as well as in industries, over the last decade. It has many properties to be explored, such as an enhanced specific surface area and beneficial thermal and electrical conductivities. Graphene is arranged as a 2D structure by organizing sp2 hybridized C with alternative single and double bonds, providing an extended conjugation combining hexagonal ring structures to form a honeycomb structure. The precious structure and outstanding characteristics are the major reason that modern industry relies heavily on graphene, and it is predominantly applied in electronic devices. Nowadays, lithium-ion batteries (LIBs) foremostly utilize graphene as an anode or a cathode, and are combined with polymers to use them as polymer electrolytes. After three decades of commercialization of the lithium-ion battery, it still leads in consumer electronic society due to its higher energy density, wider operating voltages, low self-discharge, noble high-temperature performance, and fewer maintenance requirements. In this review, we aim to give a brief review of the domination of graphene and its applications in LIBs.
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CiteScore
6.30
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