Zhuangzhuang Chu , Dongdong Chen , Qiyao Huang , Yongtao Li , Zhenzeng Wu , Yu Yang , Zhuohong Yang
{"title":"聚合物辅助制备多孔木基金属复合材料用于有机污染物的高效催化还原","authors":"Zhuangzhuang Chu , Dongdong Chen , Qiyao Huang , Yongtao Li , Zhenzeng Wu , Yu Yang , Zhuohong Yang","doi":"10.1016/j.indcrop.2022.115387","DOIUrl":null,"url":null,"abstract":"<div><p>The unreasonable emission of nitroaromatic organic pollutants (NOPs) has threatened the ecological environment. However, the existing catalytic materials for NOPs reduction can not meet the actual practical application due to various functional deficiencies. In this work, novel cellulose–based metallic composites with high catalytic activity for NOPs reduction were developed through polymer–assisted electroless deposition (ELD) technique coating metallic nanoparticles onto cellulose–based porous wood surfaces. The fabricated metallic composites display outstanding catalytic ability, catalytic universality and excellent durability for most NOPs, due to the uniform catalytic metal coating enabled by polymer–assisted ELD approach and sufficient catalytic sites provided by the porous wood host surfaces. The continuous flow catalytic systems using the fabricated bulk composites were further demonstrated showing the broad prospects of such designed metallic composites in actual practical applications. This work provides a new avenue to realize rational design and large–scale fabrication of novel high–performance catalysts for NOPs reduction applications.</p></div>","PeriodicalId":13581,"journal":{"name":"Industrial Crops and Products","volume":"187 ","pages":"Article 115387"},"PeriodicalIF":5.6000,"publicationDate":"2022-11-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Polymer–assisted preparation of porous wood–based metallic composites for efficient catalytic reduction of organic pollutants\",\"authors\":\"Zhuangzhuang Chu , Dongdong Chen , Qiyao Huang , Yongtao Li , Zhenzeng Wu , Yu Yang , Zhuohong Yang\",\"doi\":\"10.1016/j.indcrop.2022.115387\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>The unreasonable emission of nitroaromatic organic pollutants (NOPs) has threatened the ecological environment. However, the existing catalytic materials for NOPs reduction can not meet the actual practical application due to various functional deficiencies. In this work, novel cellulose–based metallic composites with high catalytic activity for NOPs reduction were developed through polymer–assisted electroless deposition (ELD) technique coating metallic nanoparticles onto cellulose–based porous wood surfaces. The fabricated metallic composites display outstanding catalytic ability, catalytic universality and excellent durability for most NOPs, due to the uniform catalytic metal coating enabled by polymer–assisted ELD approach and sufficient catalytic sites provided by the porous wood host surfaces. The continuous flow catalytic systems using the fabricated bulk composites were further demonstrated showing the broad prospects of such designed metallic composites in actual practical applications. This work provides a new avenue to realize rational design and large–scale fabrication of novel high–performance catalysts for NOPs reduction applications.</p></div>\",\"PeriodicalId\":13581,\"journal\":{\"name\":\"Industrial Crops and Products\",\"volume\":\"187 \",\"pages\":\"Article 115387\"},\"PeriodicalIF\":5.6000,\"publicationDate\":\"2022-11-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial Crops and Products\",\"FirstCategoryId\":\"97\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0926669022008706\",\"RegionNum\":1,\"RegionCategory\":\"农林科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"AGRICULTURAL ENGINEERING\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial Crops and Products","FirstCategoryId":"97","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0926669022008706","RegionNum":1,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"AGRICULTURAL ENGINEERING","Score":null,"Total":0}
Polymer–assisted preparation of porous wood–based metallic composites for efficient catalytic reduction of organic pollutants
The unreasonable emission of nitroaromatic organic pollutants (NOPs) has threatened the ecological environment. However, the existing catalytic materials for NOPs reduction can not meet the actual practical application due to various functional deficiencies. In this work, novel cellulose–based metallic composites with high catalytic activity for NOPs reduction were developed through polymer–assisted electroless deposition (ELD) technique coating metallic nanoparticles onto cellulose–based porous wood surfaces. The fabricated metallic composites display outstanding catalytic ability, catalytic universality and excellent durability for most NOPs, due to the uniform catalytic metal coating enabled by polymer–assisted ELD approach and sufficient catalytic sites provided by the porous wood host surfaces. The continuous flow catalytic systems using the fabricated bulk composites were further demonstrated showing the broad prospects of such designed metallic composites in actual practical applications. This work provides a new avenue to realize rational design and large–scale fabrication of novel high–performance catalysts for NOPs reduction applications.
期刊介绍:
Industrial Crops and Products is an International Journal publishing academic and industrial research on industrial (defined as non-food/non-feed) crops and products. Papers concern both crop-oriented and bio-based materials from crops-oriented research, and should be of interest to an international audience, hypothesis driven, and where comparisons are made statistics performed.