聚丙烯酰胺基水凝胶在低分子盐水溶液中的溶胀

E. Vorobieva
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引用次数: 3

摘要

研究了交联聚丙烯酰胺的溶胀动力学与外源溶液组成的关系。结果表明,聚合物凝胶溶胀在从水到氯化钾或氯化钠溶液的过渡过程中急剧减小,反之亦然,然后逐渐增大。凝胶在氯化钠溶液中的溶胀比在氯化钾溶液中的溶胀大。在平衡膨胀凝胶中,凝胶相中盐的浓度高于外溶液,并随着从氯化钾到氯化钠的转变而增加。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Swelling of polyacrylamide-based hydrogel in aqueous solutions of low-molecular salts
The swelling kinetics of cross-linked polyacrylamide was studied depending on the composition of the external solution. It was shown that the polymer gel swelling during the transition from water to a potassium or sodium chloride solution and vice versa sharply decreases, then gradually increases. The swelling of gel in a solution of sodium chloride is higher than that of potassium chloride. In the equilibrium swollen gel, the concentration of salts in the gel phase is higher than in the external solution and increases with the transition from potassium chloride to sodium chloride.
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