{"title":"ÃÂ5甾体化合物烯丙基氧化制烯酮方法综述","authors":"Wendell Sg, Edwards Jp","doi":"10.4172/2157-7536.1000171","DOIUrl":null,"url":null,"abstract":"Introduction of α, β-unsaturated ketones to Δ5 steroidal olefins changes the characteristics and biological function of those compounds. Several synthetic methods have been reported to accomplish carbonyl introduction to Δ5 steroidal olefins. Herein, this short review will catalogue many of those oxidative methods, particularly those proceeding through a peroxide intermediate and/or use chromium complexes as reagents.","PeriodicalId":17132,"journal":{"name":"Journal of steroids & hormonal science","volume":"3 1","pages":"1-5"},"PeriodicalIF":0.0000,"publicationDate":"2016-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"A Short Review of Methods for the Allylic Oxidation of ÃÂ5 SteroidalCompounds to Enones\",\"authors\":\"Wendell Sg, Edwards Jp\",\"doi\":\"10.4172/2157-7536.1000171\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Introduction of α, β-unsaturated ketones to Δ5 steroidal olefins changes the characteristics and biological function of those compounds. Several synthetic methods have been reported to accomplish carbonyl introduction to Δ5 steroidal olefins. Herein, this short review will catalogue many of those oxidative methods, particularly those proceeding through a peroxide intermediate and/or use chromium complexes as reagents.\",\"PeriodicalId\":17132,\"journal\":{\"name\":\"Journal of steroids & hormonal science\",\"volume\":\"3 1\",\"pages\":\"1-5\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2016-04-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of steroids & hormonal science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4172/2157-7536.1000171\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of steroids & hormonal science","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4172/2157-7536.1000171","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A Short Review of Methods for the Allylic Oxidation of ÃÂ5 SteroidalCompounds to Enones
Introduction of α, β-unsaturated ketones to Δ5 steroidal olefins changes the characteristics and biological function of those compounds. Several synthetic methods have been reported to accomplish carbonyl introduction to Δ5 steroidal olefins. Herein, this short review will catalogue many of those oxidative methods, particularly those proceeding through a peroxide intermediate and/or use chromium complexes as reagents.
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