三价金属离子混合配体配合物的合成及光谱研究

F. Y. Larial, M. El-ajaily, N. M. El-Barasi, A. Maihub, R. Mohapatra, T. AL-Noor
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引用次数: 0

摘要

以2-氨基酚和2-羟基苯乙酮(HL1)为一级配体,以邻氨基苯甲酸(L2)为二级配体,通过缩合反应得到了Cr(III)、Fe(III)和La(III)离子与席夫碱相互作用的新型三种混合配体配合物。合成了所形成的混合配体配合物,并利用元素分析、红外光谱、核磁共振、紫外可见光谱和质谱以及摩尔电导和磁性测量对其进行了表征。结果表明,混合配体配合物以1:1:1[L1ML2]的比例形成,具有非电解性质。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis and Spectral Studies of Mixed Ligand Complexes of Trivalent Metal Ions
Novel three mixed ligand complexes derived from the interaction of Cr(III), Fe(III) and La(III) ions with a Schiff base resulted from the condensation process of 2-aminophenol and 2-hydroxy acetophenone(HL1) as a primary ligand (HL1) and anthranilic acid (L2) as a secondary ligand. The formed mixed ligand complexes were synthesized and characterized using elemental analysis, FTIR, 1HNMR, UV–visible and mass spectroscopy as well as molar conductance and magnetic measurements. The obtained results revealed that the mixed ligand complexes were formed in 1:1:1[L1ML2] ratio and non-electrolytic in nature.
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