石墨烯在沙质土壤中应用以提高持水能力的见解

IF 0.8 Q4 WATER RESOURCES
L. Alessandrino, M. Mastrocicco
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引用次数: 1

摘要

在本研究中,通过淋滤柱实验,监测了石墨烯在钙质砂土和硅塑性河流土中引入后引起的相关水力参数(即水力电导率、总孔隙率和有效孔隙率、比保留率和纵向分散性)的变化,并建立了模型。采用恒压头试验计算每个柱的水力导率,同时进行浸出试验以估计总孔隙率和比保留率,每种处理进行3次重复。然后通过低流量蠕动泵在饱和条件下运行色谱柱并监测氯化物浓度。利用CXTFIT 2.0对柱状实验进行反演,反演有效孔隙度和纵向分散度。结果表明,添加石墨烯后,两种土壤的导电性和孔隙度都发生了微小变化。与对照列相比,在修改后的列中记录了特定保留值的显著增加。氯化物突破曲线模型显示,石墨烯在钙质沙质土壤中的分散性比对照提高了一倍,而在硅塑性河流土壤中的分散性比对照降低了一半。研究结果表明,石墨烯使沙质土壤保留孔隙水的能力发生正向变化,但同时也改变了溶质传输参数,如分散性,这表明进一步的研究需要集中于使用几种暴露浓度、持续时间和暴露方式,并应用模拟现场条件或在真实现场条件下进行实验,以了解不需要的化合物在经石墨烯改性的土壤中的结局。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Insight on the application of graphene to sandy soils to improve water holding capacity
In this study, the changes in relevant hydraulic parameters (namely hydraulic conductivity, total and effective porosity, specific retention, and longitudinal dispersivity) induced by the introduction of graphene in a calcareous sandy soil and a siliciclastic riverine soil were monitored and modelled via leaching column experiments. Constant pressure head tests were used to calculate the hydraulic conductivity of each column, while leaching experiments were run to estimate total porosity and specific retention, and for each treatment three replicates were done. Columns were then run under saturated conditions via a low flow peristaltic pump and monitored for chloride concentrations. CXTFIT 2.0 was employed to inversely model the column experiments and retrieve effective porosity and longitudinal dispersivity. Results highlighted small changes of hydraulic conductivity and porosity, induced by graphene addition for both soils. A marked increase of specific retention values was instead recorded in the amended columns respect to control ones. Chloride breakthrough curves modelling showed that graphene doubled dispersivity in the calcareous sandy soil compared to the control, while it halved dispersivity in the siliciclastic riverine soil with respect to the control. The results highlight that graphene induces positive shift in the capacity of sandy soil to retain porewater but at the same time it also alters solute transport parameters, like dispersivity, suggesting that further studies need to focus on using several exposure concentrations, durations and mode of exposure, and apply simulated field conditions or perform experiments in real field conditions, to understand the fate of unwanted compound in soils amended with graphene.
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来源期刊
CiteScore
1.80
自引率
50.00%
发文量
36
审稿时长
8 weeks
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