双-(硝基苯甲酸酯)-二-(吡嗪)镍(ii)-二水合物的合成、理化研究及晶体结构

S. Hasanova
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引用次数: 0

摘要

合成了新型对硝基苯甲酸与吡嗪配合物Ni(II)的分子结构,并对其分子结构进行了解码。发现中心原子与对硝基苯甲酸配体按单齿型配位。它具有吡嗪分子的基本性质,通过给体氮原子在给体-受体键中由镍原子配位。两个水分子通过给体氧原子与镍配位,使其配位数为6。吡嗪分子在给体氮原子的帮助下交联对硝基苯甲酸镍(II)分子,形成聚合物分子
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SYNTHESIS, PHYSICOCHEMICAL STUDY AND CRYSTAL STRUCTURE OF BIS-(PNITROBENZOATE)-DI-(PYRAZINE) NICKEL(II)-DIHYDRATE
The molecular structure of the new Ni(II) complex of p-nitrobenzoic acid and pyrazine was synthesized and deciphered. It found that the central atom was coordinated by the ligand of p-nitrobenzoic acid according to the monodentate type. Having the basic properties of the pyrazine molecule, it was coordinated by the nickel atom in a donor-acceptor type of bond through donor nitrogen atoms. Two water molecules through donor oxygen atoms were coordinated by nickel and complement its coordination number to six. Pyrazine molecules cross-link para-nitrobenzoate Ni(II) molecules with the help of donor nitrogen atoms and form polymeric molecules
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CiteScore
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