{"title":"用于水介质中绿色光催化脱氢的无金属和水兼容纳米催化剂","authors":"","doi":"10.1016/j.gresc.2023.03.001","DOIUrl":null,"url":null,"abstract":"<div><p>Two types of poly-porphyrin-based heterogeneous photocatalysts including insoluble polymer and water-soluble nanoparticles exhibited excellent photocatalytic activity in visible-light-induced dehydrogenation in water. The extremely low catalyst loading (0.01 mol%) of water-soluble nanoparticles provided so far the highest turnover frequency (TOF) value (333 h<sup>-1</sup>) for such transformation among reported records.</p></div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 3","pages":"Pages 186-190"},"PeriodicalIF":0.0000,"publicationDate":"2024-08-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666554923000285/pdfft?md5=8ebe2be535bad39e84ce35d0ab7ac238&pid=1-s2.0-S2666554923000285-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Metal-free and water-compatible nanocatalysts for green photocatalytic dehydrogenation in aqueous medium\",\"authors\":\"\",\"doi\":\"10.1016/j.gresc.2023.03.001\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Two types of poly-porphyrin-based heterogeneous photocatalysts including insoluble polymer and water-soluble nanoparticles exhibited excellent photocatalytic activity in visible-light-induced dehydrogenation in water. The extremely low catalyst loading (0.01 mol%) of water-soluble nanoparticles provided so far the highest turnover frequency (TOF) value (333 h<sup>-1</sup>) for such transformation among reported records.</p></div>\",\"PeriodicalId\":12794,\"journal\":{\"name\":\"Green Synthesis and Catalysis\",\"volume\":\"5 3\",\"pages\":\"Pages 186-190\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-08-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666554923000285/pdfft?md5=8ebe2be535bad39e84ce35d0ab7ac238&pid=1-s2.0-S2666554923000285-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Synthesis and Catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666554923000285\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Synthesis and Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666554923000285","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Metal-free and water-compatible nanocatalysts for green photocatalytic dehydrogenation in aqueous medium
Two types of poly-porphyrin-based heterogeneous photocatalysts including insoluble polymer and water-soluble nanoparticles exhibited excellent photocatalytic activity in visible-light-induced dehydrogenation in water. The extremely low catalyst loading (0.01 mol%) of water-soluble nanoparticles provided so far the highest turnover frequency (TOF) value (333 h-1) for such transformation among reported records.
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