{"title":"氢-氮和氢-二氧化碳混合气体的导热性","authors":"P. Mukhopadhyay, A. Gupta, A. K. Barua","doi":"10.1088/0508-3443/18/9/312","DOIUrl":null,"url":null,"abstract":"The thermal conductivity of H2-N2 and H2-CO2 mixtures has been measured from -15 to 200°C by using the thick-wire variant of the hot-wire method. The experimental values have been compared with those calculated from the Hirschfelder-Eucken formula. Although fairly satisfactory agreement between theory and experiment is obtained it appears that for a precise interpretation of the thermal conductivity of polyatomic gas mixtures a better representation of the cross-relaxation phenomena is necessary.","PeriodicalId":9350,"journal":{"name":"British Journal of Applied Physics","volume":"18 1","pages":"1301-1306"},"PeriodicalIF":0.0000,"publicationDate":"1967-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"19","resultStr":"{\"title\":\"Thermal conductivity of hydrogen-nitrogen and hydrogen-carbon-dioxide gas mixtures\",\"authors\":\"P. Mukhopadhyay, A. Gupta, A. K. Barua\",\"doi\":\"10.1088/0508-3443/18/9/312\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The thermal conductivity of H2-N2 and H2-CO2 mixtures has been measured from -15 to 200°C by using the thick-wire variant of the hot-wire method. The experimental values have been compared with those calculated from the Hirschfelder-Eucken formula. Although fairly satisfactory agreement between theory and experiment is obtained it appears that for a precise interpretation of the thermal conductivity of polyatomic gas mixtures a better representation of the cross-relaxation phenomena is necessary.\",\"PeriodicalId\":9350,\"journal\":{\"name\":\"British Journal of Applied Physics\",\"volume\":\"18 1\",\"pages\":\"1301-1306\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1967-09-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"19\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"British Journal of Applied Physics\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1088/0508-3443/18/9/312\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"British Journal of Applied Physics","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1088/0508-3443/18/9/312","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Thermal conductivity of hydrogen-nitrogen and hydrogen-carbon-dioxide gas mixtures
The thermal conductivity of H2-N2 and H2-CO2 mixtures has been measured from -15 to 200°C by using the thick-wire variant of the hot-wire method. The experimental values have been compared with those calculated from the Hirschfelder-Eucken formula. Although fairly satisfactory agreement between theory and experiment is obtained it appears that for a precise interpretation of the thermal conductivity of polyatomic gas mixtures a better representation of the cross-relaxation phenomena is necessary.