Zamroni Dita Firdaus, Firza Okta Sumarmiyati, B. Wahyudi, Sd Sumbogo Murti
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引用次数: 0

摘要

木棉籽油、麻疯树籽油和CPO劣质油是不能用作食品原料的植物油,但具有很大的生物燃料潜力,如绿色柴油,可以直接使用,而不需要添加柴油。绿色柴油的生产包括原料预处理和绿色柴油的合成。本研究的目的是用三种原料制备绿色柴油,并对催化剂CoMo/ α -Al 2o3和NiMo/ α -Al 2o3的加氢工艺进行研究,以满足SNI生物柴油的要求。在催化剂加氢间歇反应器中,初始压力为30 bar,第一反应阶段温度为300℃,反应1小时,第二反应阶段温度为400℃,反应1小时,开始制造绿色柴油。采用NiMo/ α -Al 2o3催化剂,在CPO脱品位上获得了最佳的绿色柴油效果,产率为96.4626%。表征结果表明,硫含量、倾点、热值、GC-FID液、闪点、密度、十六烷数满足SNI生物柴油标准,但运动粘度值不满足SNI生物柴油标准。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
SINTESIS GREEN DIESEL DARI VARIASI FEEDSTOCK DAN KATALIS DENGAN PROSES HIDROGENASI
Kapok seed oil, jatropha seed oil, and CPO Off-grade are vegetable oils that cannot used as food ingredients, but have great potential biofuels such as green diesel which can be directly applied without the addition of diesel. Making green diesel consists of pretreatment of raw materials and synthesis of green diesel. The purpose of this research is to make green diesel from three raw materials and variation of catalysts CoMo/ɣ-Al 2 O 3 and NiMo/ɣ-Al 2 O 3 used hydrogenation process that fulfill SNI Biodiesel. Making green diesel starts with giving initial pressure of 30 bar, temperature of 300 o C for the reaction stage 1 for 1 hour, and 400ºC for stage 2 for 1 hour in batch hydrogenation reactor of catalyst addition. The best green diesel results were obtained on CPO Off-grade using NiMo/ɣ-Al 2 O 3 catalyst with %yield of 96.4626%. The characterization results obtained that sulfur content, pour point, calorific value, GC-FID liquid, flash point, density, and cetane number fulfill the SNI biodiesel standard, but the kinematic viscosity value does not fulfill the SNI biodiesel standard.
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