氧化铝碳热还原制铝加热温度的优化

A. Chahtou, Rabie Benioub, K. Itaka
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引用次数: 1

摘要

近年来,基于铝的表面等离子体共振传感器(SPR)在化学和生物医学领域的实时、无标签和多路检测的研究引起了人们的广泛关注,因为铝与传统贵金属(如银和金)相比具有有效的稳定性。目前,电解Hall-Heroult工艺代表了从氧化铝中生产铝的常规和商业化工艺。然而,由于其巨大的能源需求,以及涉及到最终产品的许多副过程,该过程的成本较高。为了克服传统工艺的这些优点,本文研究了采用感应加热炉,以碳为还原剂的氧化铝碳热还原工艺,以确定获得较高收率的最佳加热温度条件。铝-氧-碳的相图是相当有价值的资产。因此,对其进行了模拟,并从理论上确定了实验过程所用的温度和气体条件。通过对实验结果的分析,比较了不同加热温度下得到的Al产率,确定了最佳加热温度为1750℃。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Optimization of heating-temperature on carbothermal reduction of alumina for production of aluminum
Recently the study of aluminum-based surface plasmon resonance sensors (SPR) for real-time, label-free, and multiplexed detections for chemical and biomedical applications have attracted a considerable attention due to the effective stability of aluminum compared to conventional noble metals such as Ag and Au. Currently, the electrolytic Hall-Heroult process represents the conventional and commercialized process for the production of aluminum from alumina. However, this process suffers from higher cost due to its immense energy requirements, and a number of by-processes implicated to reach the final product. In this paper, to overcome such advantages of the conventional process, the carbothermal reduction process of alumina using an induction heating furnace and carbon as a reductant agent were investigated to determine the optimum heating temperature condition for the achievement of a higher yield of the process. The phase diagram for the aluminum-oxygen-carbon represents quite a valuable asset. Therefore it was simulated and used to determine theoretically the temperature and gas conditions used for the experimental process. The optimum heating temperature of 1750oC was determined based on the analyzing of the experimental results based on the comparison of the obtained Al yield for various heating temperature profiles.
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