E. Jakusek, H.A. Kołodziej, M. Rozpenk, S. Sorriso ∗
{"title":"甲酰基、羧基和1,1′-二氯二茂铁的介电吸收和分子动力学","authors":"E. Jakusek, H.A. Kołodziej, M. Rozpenk, S. Sorriso ∗","doi":"10.1016/0378-4487(82)80003-4","DOIUrl":null,"url":null,"abstract":"<div><p>Dielectric spectra of formyl-, carboxyl-, and 1,1′-dichloro-ferrocene have been examined in benzene in the frequency range of 100 MHz-26 GHz, at various temperatures. In these conditions only one clear dielectric absorption band has been observed and a Debye-type behaviour has been found. Calculation of the macroscopic dielectric relaxation times and the thermodynamic parameters has also been performed. All evidence seems to suggest a type of mechanism for dielectric relaxation, even if at the present stage of research it might be prudent not to indicate a definitive model for the molecular dynamics itself of these compounds.</p></div>","PeriodicalId":100049,"journal":{"name":"Advances in Molecular Relaxation and Interaction Processes","volume":"22 3","pages":"Pages 167-176"},"PeriodicalIF":0.0000,"publicationDate":"1982-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0378-4487(82)80003-4","citationCount":"3","resultStr":"{\"title\":\"Dielectric absorption and molecular dynamics of formyl-, carboxyl-, and 1,1′-dichloro-ferrocene\",\"authors\":\"E. Jakusek, H.A. Kołodziej, M. Rozpenk, S. Sorriso ∗\",\"doi\":\"10.1016/0378-4487(82)80003-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Dielectric spectra of formyl-, carboxyl-, and 1,1′-dichloro-ferrocene have been examined in benzene in the frequency range of 100 MHz-26 GHz, at various temperatures. In these conditions only one clear dielectric absorption band has been observed and a Debye-type behaviour has been found. Calculation of the macroscopic dielectric relaxation times and the thermodynamic parameters has also been performed. All evidence seems to suggest a type of mechanism for dielectric relaxation, even if at the present stage of research it might be prudent not to indicate a definitive model for the molecular dynamics itself of these compounds.</p></div>\",\"PeriodicalId\":100049,\"journal\":{\"name\":\"Advances in Molecular Relaxation and Interaction Processes\",\"volume\":\"22 3\",\"pages\":\"Pages 167-176\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1982-03-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0378-4487(82)80003-4\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Advances in Molecular Relaxation and Interaction Processes\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0378448782800034\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Advances in Molecular Relaxation and Interaction Processes","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0378448782800034","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Dielectric absorption and molecular dynamics of formyl-, carboxyl-, and 1,1′-dichloro-ferrocene
Dielectric spectra of formyl-, carboxyl-, and 1,1′-dichloro-ferrocene have been examined in benzene in the frequency range of 100 MHz-26 GHz, at various temperatures. In these conditions only one clear dielectric absorption band has been observed and a Debye-type behaviour has been found. Calculation of the macroscopic dielectric relaxation times and the thermodynamic parameters has also been performed. All evidence seems to suggest a type of mechanism for dielectric relaxation, even if at the present stage of research it might be prudent not to indicate a definitive model for the molecular dynamics itself of these compounds.