聚氨酯:最近的工程贡献

D. Feldman
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引用次数: 0

摘要

聚氨酯是最通用的聚合物之一,具有广泛的可调性能,如化学稳定性,柔韧性,耐磨性和耐划伤性,韧性和可生物降解性。它是一种独特的聚合物,含有软段和硬段交替。本文综述了最近(2018-2019)在聚氨酯泡沫、涂料、粘合剂、密封剂、弹性体、复合材料的合成、性能和应用方面所做的工程研究贡献,并坚持了与聚氨酯可燃性和声学相关的重要方面和实现。2,2,3,3,4,:七氟丁酸2,2-二羟基甲基丁基酯;HRR:放热速率;HPU:超支化聚氨酯;LMPET:低熔点聚酯;LOI:限氧指数;MW:分子量;PEG:聚乙二醇;峰值放热速率;PPG:聚丙二醇;POSS多面体低聚硅氧烷;菩:聚氨酯;PU FR:含FR的聚氨酯;RO:菜籽油;SEM:扫描电子显微镜;SPB:豆油基多元醇;TEM:透射电子显微镜;TGA:热重分析;THRR:总放热率;THR:总放热量;TPIA: Acylhydrazine;TPID:二硫键;TPU:热塑性聚氨酯;研究了新型木质素生物基聚氨酯涂料。由木质素衍生的香草酸得到的一种二异氰酸酯,与三种不同的非化学改性技术木质素即温和的丙酮有机溶剂、硫酸盐和苏打交联。研究结果表明,木质素衍生生物基二异氰酸酯的反应为TPU涂层的生产提供了一条有趣的途径。研究还表明,木质素衍生的生物基二异氰酸酯的反应
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Polyurethane: Recent Engineering Contributions
Polyurethane is one of the most versatile polymers which stands out with a wide range of tunable properties such as chemical stability, flexibility, abrasion and scratch resistance, toughness and biodegradability. It is a unique polymer containing alternating soft and hard segments. This review covers the most recent (2018-2019) engineering research contributions done for the synthesis, properties and applications of the polyurethane foams, coatings, adhesives, sealants, elastomers, composites and insists on the important aspects and realizations related to the polyurethane flammability and acoustic. 2,2,3,3,4,: heptafluoro-butiric acid 2,2-bis-hydroxymethyl-butyl ester; HRR: Heat release rate; HPU: Hyper Branched Polyurethane; LMPET: Low Melting Polyester; LOI: Limited Oxygen Index; MW: Molecular Weight; PEG: Poly(ethylene glycol); PHRR: Peak Heat Release Rate; PPG: Poly (propylene glycol); POSS Polyhedral Oligomeric Silsequioxanes; PU: Polyurethane; PU FR: Polyurethane with FR; RO: Rape seed oil; SEM: Scanning Electron Microscopy; SPB: Soybean Oil Based Polyol; TEM: Transmission Electron microscopy; TGA: Thermo gravimetry analysis; THRR: Total heat release rate; THR: Total heat release; TPIA: Acylhydrazine; TPID: Disulfide bonds; TPU: Thermoplastic polyurethane; VOCs: Volatile organic compounds New biobased PU coatings with lignin were studied. A diisocyanate obtained from lignin-derived vanilic acid and crosslinked with three different nonchemically modified technical lignins namely mild acetone organosolv, kraft, and soda. The results of the research showed that the reaction of a lignin-derived biobased diisocyanate represent an interesting way for the production of TPU coating. The study also showed that the reaction of lignin-derived biobased diisocyanate
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