电荷复合抑制CdSeS/CdSe/ZnS QDSSC设计

Erdem Eli̇bol
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引用次数: 2

摘要

量子敏化太阳能电池(quantum sensitized solar cells, QDSSC)在理论上可以达到能量转换,具有理论上较高的效率值,在量子敏化太阳能电池的研究中获得的兴趣远远不够,这表明量子敏化太阳能电池技术还有许多有待解决的困难。QDSSC技术面临的主要挑战之一是在QDSSC中发生辐照负荷重组。因此,在本研究中,使用CdSeS量子点作为文献中最常用的CdS量子点的替代品,以支持tio2表面与电解质和量子点表面之间的负载复合。在本研究中,CdS和CdSeS量子点采用SILAR法在tio2表面进行包覆,而之前合成的CdSe量子点采用化学深沉积法进行包覆。表面最后用ZnS量子点处理。通过优化研究,确定了QDSSCs的理想CdSeS涂层数量。结果表明,tio2 /CdSeS 4 /CdSe/ZnS QDSSCs的Jsc和Voc值分别为8.799 mA/ cm2和0.795 V, PCE值提高到4.452%。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Charge recombination suppressed CdSeS/CdSe/ZnS QDSSC design
he interest in quantum sensitized solar cells (QDSSC), which theoretically to up to energy con version is it has theoretically high efficiency value, obtained in studies with QDSSCs is far these This shows that there are many difficulties to be solved in QDSSC technology. One of the main challenges in QDSSC technology is irradiated load recombination occurring in QDSSC. For this reason, in this study, it is about using CdSeS QDs as an alternative to the most used CdS QDs in the literature in order to supp ress the load recombination between TiO 2 surface and electrolyte and QD surfaces. In the study, while CdS and CdSeS QDs were coated on the TiO 2 surface with SILAR method, the previously synthesized CdSe QD was coated with chemical deep deposition method. Surfaces were last treated with ZnS QDs. An optimization study was carried out to determine the ideal number of CdSeS coatings for QDSSCs. As a result, the Jsc and Voc values for TiO 2 /CdSeS 4 /CdSe/ZnS QDSSCs were 8.799 mA/ cm 2 and 0.795 V, respectively, while the PCE value increased to 4.452%.
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