超级电容器电极用空心纳米结构钴金属有机骨架的合成

Wenlu Xuan, R. Ramachandran, Changhui Zhao, Fei Wang
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引用次数: 4

摘要

采用水热法合成了钴金属有机骨架(Co-MOF),并将其作为修饰电极应用于超级电容器中。采用扫描电镜、透射电镜、x射线衍射、brunauer - emmet - teller分析仪等多种技术对Co-MOF结构和文本特征进行了研究。Co-MOF的中空结构具有较高的比表面积。通过循环伏安法、恒流充放电试验和电化学阻抗谱分析了制备的Co-MOF的电化学行为。结果表明,由于Co-MOF具有较高的比表面积和大量的介孔空隙,促进了电解质离子的运输,具有良好的电容稳定性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Synthesis of Hollow Nano-Structured Cobalt Metal-Organic Framework for Supercapacitor Electrodes
Cobalt metal-organic framework (Co-MOF) has been synthesized using a hydrothermal method and applied as Co-MOF modified electrode in supercapacitors. Multiple techniques like scanning electron microscope, transmission electron microscope, X-ray diffraction and Brunauer-Emmett-Teller analyzer were employed to investigate Co-MOF structure and textual characteristics. Co-MOF has high specific surface area due to the hollow structure with mesopore voids. The electrochemical behavior of the as-prepared Co-MOF was analyzed by cyclic voltammetry, galvanostatic charge-discharge tests and electrochemical impedance spectroscopy. The results exhibit good capacitive behavior of Co-MOF because the high specific surface area and numerus mesopore voids promote the transportation of electrolyte ions, which shows good capacitive stability as a supercapacitor electrode.
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