马库斯的电子转移理论，有毒化合物的分选装置

Advances in Free Radical Biology & Medicine Pub Date : 1985-01-01 DOI:10.1016/8755-9668(85)90004-3

Lennart Eberson

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引用次数: 27

摘要

提出了外球(非键)电子转移反应的马库斯理论。此外，它被应用于识别能够通过快速电子转移到或从氧化还原蛋白产生自由基离子和/或自由基的化合物的问题。通过几个涉及不同类型的异种抗生素的例子来说明马库斯疗法的使用。

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The Marcus theory of electron transfer, a sorting device for toxic compounds

The Marcus theory for outer-sphere (non-bonded) electron transfer reactions is presented. In addition, it is applied to the problem of identifying compounds capable of generating radical ions and/or radicals $via$ fast electron transfer to or from redox proteins. The use of the Marcus treatment is illustrated by several examples involving different types of xenobiotics.

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Advances in Free Radical Biology & Medicine

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