航空航天锂离子电池的退化

Linda J. Bolay, T. Schmitt, O. S. Mendoza-Hernandez, Y. Sone, A. Latz, Birger Horstmann
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引用次数: 3

摘要

锂离子电池由于其性能和长期稳定性而成为广泛应用的首选技术。锂离子电池的性能和耐久性受到多种降解机制的影响。这包括固体电解质界面(SEI)的生长和金属锂在负极表面的沉积,称为锂电镀。对于这两个过程,我们都开发了基于物理的模型。在本文中,我们开发了一个模型来描述由日本宇宙航空研究开发机构开发的在轨卫星REIMEI的电池性能和寿命。我们扩展了现有的SEI生长模型,并将其纳入新鲜细胞的模型中。然后在一维和三维模拟了电池在循环下的退化。为了验证该模型,我们使用了电池的实验和飞行数据。我们发现循环后SEI厚度的不均匀性。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Degradation of Lithium-Ion Batteries in Aerospace
Lithium-ion batteries are the technology of choice for a broad range of applications due to their performance and long-term stability. The performance and durability of lithiumion batteries is impacted by various degradation mechanisms. These include the growth of the solid-electrolyte interphase (SEI) and the deposition of metallic lithium on the surface of the negative electrode, referred to as lithium plating. For both processes we develop physically based models. In this contribution we develop a model to describe the performance and lifetime of the batteries of in-orbit satellite REIMEI developed by the Japan Aerospace Exploration Agency. We extend an existing model for SEI growth and incorporate it into a model for fresh cells. Then we simulate the degradation of batteries under cycling in 1D and 3D. To validate the model, we use experimental and in-flight data of the batteries. We show inhomogeneities in the SEI thickness after cycling.
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