指数

M. Pye
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引用次数: 0

摘要

绝对硬度定义99年98表的数据,100年,101年和60 p受体定义缩醛异头效应在78年,79年激进分子袭击279年,296丙酮96,135,292,293,308 135 233 Acetoxycyclopentadiene 180 Acetoxybutadiene乙酰苯乙酮,Z-substituent 59乙炔,看到炔烃Acetyltrimethylsilane 96酸性氯化物,134年的亲电性,135吖啶酮,323年化学发光产品,324丙烯醛140,224,227,236年62年234年前沿轨道的二聚作用,63年,141年,228年,234在Diels-Alder反应235 54分子轨道电离势61,62光化学309,312质子化FOs 141模型为刘易斯酸配位239区域选择性在Diels-Alder反应230丙烯酸酯,见丙烯酸乙酯;丙烯酸甲酯丙烯腈环加成二甲烯256 Diels-Alder与tropone反应233杂基Diels-Alder反应235与丙酮反应308光二聚化309自由基攻击289 Diels-Alder反应区域选择性230酰基阳离子,光- fries重排不稳定65酰基自由基322 Adamantanones产物化学发光323,324立体化学攻击182加成反应抗markovnikov 291297对烯烃的自由基279对烯烃的立体特异性抗162 166的加消亲电取代167 166的亲核取代
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Index
Absolute hardness defined 98 tables of data 99, 100, 101 and p Acceptors defined 60 Acetals anomeric effect in 78, 79 radical attack on 279, 296 Acetone 96, 135, 292, 293, 308 Acetophenone 135 Acetoxybutadiene 233 Acetoxycyclopentadiene 180 Acetyl, as a Z-substituent 59 Acetylene, see Alkynes Acetyltrimethylsilane 96 Acid chlorides, electrophilicity of 134, 135 Acridone, product in chemoluminescence 323, 324 Acrolein 140, 224, 227, 236 dimerisation of 234 frontier orbitals of 62, 63, 141, 228, 234 in hetero Diels-Alder reactions 235 ionisation potential of 54 molecular orbitals of 61, 62 photochemistry of 309, 312 protonated FOs of 141 model for Lewis acid coordination as 239 regioselectivity of in Diels-Alder reactions 230 Acrylate, see Ethyl acrylate; Methyl acrylate Acrylonitrile cycloaddition to dimethylallene 256 Diels-Alder reaction with tropone 233 in hetero Diels-Alder reactions 235 photochemical reaction of with acetone 308 photodimerisation of 309 radical attack on 289 regioselectivity of in Diels-Alder reactions 230 Acyl cation, destabilised 65 Acyl radical in photo-Fries rearrangement 322 Adamantanones product in chemoluminescence 323, 324 stereochemistry of attack on 182 Addition reactions anti-Markovnikov 291, 297 of radicals to alkenes 279 stereospecifically anti to alkenes 162 Addition-Elimination electrophilic substitution by 166, 167 nucleophilic substitution by 166
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