多结晶增强剂在防水混凝土中的热效应管理

Radi Al-Rashed , Maher Al-Jabari
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引用次数: 1

摘要

混凝土中的热效应与混凝土在正常条件下或在严寒条件下养护期间,或在冻融循环中,由放热水泥水化反应释放的热量有关。这些热效应可能导致开裂,影响混凝土孔隙率,影响其导热性、质量和水力导电性,从而产生重大的耐久性问题。本文对在配料时与水混合的水性防水溶液(多结晶增强剂(MCE))的热管理能力进行了实验研究。实验根据适用的ASTM程序进行,用于测量热释放率、温度分布、压缩和弯曲强度、温度-时间因子以及导热性和导电性。此外,还研究了冻融循环对混凝土质量变化率、长度变化率和相对动模量的影响。研究结果表明,添加量为水泥重量2%的MCE有可能减轻水泥水化和混凝土冷冻养护过程中的热效应,为大体积混凝土的热问题提供了解决方案。研究结果表明,MCE可以延缓放热释放,降低放热释放的速率。300次循环后,混凝土的质量变化百分比减少92%,长度变化百分比减少15%,相对动模量增加17%,从而提高混凝土抗冻融循环的能力。MCE的这些热影响还与导热系数降低16%和通过混凝土的总电荷减少90.7%有关。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Managing Thermal Effects in Waterproofed Concrete with Multi-Crystallization Enhancer

Thermal effects in concrete are associated with a heat release from the exothermic cement hydration reactions during concrete curing under normal conditions or under severe cold conditions, or when it is subjected to cycles of freezing and thawing. These thermal effects may cause cracking, impact concrete porosity and affects its thermal, mass and hydraulic conductivities, and hence create major durability problems. This paper presets an experimental study of the thermal management ability of an aqueous waterproofing solution (the Multi-Crystallization Enhancer (MCE)) that is intermixed with water at the time of batching. The experiments were performed according to the applicable ASTM procedures for measuring the rate of heat release, temperature profiles, compressive and flexural strengths, temperature-time factor and thermal and electrical conductivities. Additionally, the impact of cycles of freezing and thawing on the percentages of mass change, length change and relative dynamic modulus were investigated. The findings indicate that the addition of the MCE at a dosage of 2% of cement weight has the potential to mitigate the thermal effects during cement hydration and during curing concrete under freezing conditions providing a solution for thermal problems of mass concrete. The findings demonstrate that the MCE can delay the exothermic heat release and can reduce its rate at the initial stage. It can also increase the resistance of concrete against cycles of freezing and thawing by achieving 92% reduction in the percentage mass change, 15% reduction in the percentage length change and 17% enhancement in the relative dynamic modulus, after 300 cycles. These thermal impacts of the MCE are also associated with 16% reduction in the thermal conductivity and 90.7% reduction in the total charge passage through concrete.

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