共沉淀法合成纯和掺杂镍的硫化镉纳米颗粒的光催化活性

A. Leena, K. Raji
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引用次数: 2

摘要

硫化镉是一类重要的II-VI型半导体纳米材料,具有优异的物理性能和宽能带能,在光催化应用中得到了成功的利用。光技术是解决环境和能源问题的重要技术之一。在CdS纳米晶体中加入过渡金属离子掺杂剂是调整其物理性质的一种方便方法。本文采用共沉淀法合成了过渡金属离子镍掺杂的CdS纳米晶体。研究纯镉纳米晶和掺杂镍镉纳米晶在降解亚甲基蓝中的光催化活性,为进一步研究和在纺织废水处理中的实际应用提供实验基础。影响光催化活性的因素很多,如相组成、晶粒大小、形貌和能隙等。通过XRD、EDAX、SEM、UV、PL和FTIR等手段对合成材料的结构和光学性能进行了研究。在可见光(λmax=400 nm)照射下,利用掺杂镍的CdS纳米颗粒在光反应器容器中进行了亚甲基蓝的光催化降解。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Photocatalytic Activity of Pure and Nickel Doped Cadmium Sulphide Nanoparticles Synthesized via Co-Precipitation Method
Article history: Received 20 March 2019 Accepted 29 April 2019 Available online 04 June 2019 Cadmium sulfide is an important group of II-VI semiconducting nanomaterials with excellent physical properties and wide bandgap energy, are successful in the utilization of photocatalytic application. Photo technology is one of important technology to solve environmental and energy issues. Incorporating a transition metal ion dopant into CdS nanocrystalline is a convenient way to tailor its physical properties. In this present work, we have synthesized transition metal ion nickel doped CdS nanocrystals via coprecipitation method. The objective of this research is to investigate the photocatalytic activity of pure and nickel doped CdS nanocrystals for the degradation of methylene blue and to provide an experimental base for further study and practical application in textile effluent and wastewater treatment processes. Many factors can influence the performance of photocatalytic activity such as phase composition, crystallite size, morphology, and energy gap. The structural and optical properties of as-synthesized materials were studied by XRD, EDAX, SEM, UV, PL, and FTIR. Photocatalytic degradation of methylene blue was performed by using nickel doped CdS nanoparticles in a photoreactor vessel irradiated by visible light from the tungsten lamp (λmax=400 nm).
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