{"title":"NO 2 在NaCl表面的非均相反应研究","authors":"李宏军 朱彤 丁杰 陈琦 徐冰烨","doi":"10.1360/ZB2005-35-6-506","DOIUrl":null,"url":null,"abstract":"采用新的样品制备方法和气-固自由扩散的实验方式, 使用漫反射傅立叶转换红外光谱原位反应器, 结合离子色谱、X-射线光电子能谱、扫描电子显微镜等分析方法, 研究了NO 2 在NaCl表面的非均相反应. 研究表明反应不只是发生在颗粒物表面, 体相也参与了反应; 颗粒物表面的活性点对反应起决定作用, 同时测定了反应级数为二级, 反应摄取系数为(1.54±0.70)× 10NO −5 .","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"22 1","pages":"506-517"},"PeriodicalIF":0.0000,"publicationDate":"2005-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"NO 2 在NaCl表面的非均相反应研究\",\"authors\":\"李宏军 朱彤 丁杰 陈琦 徐冰烨\",\"doi\":\"10.1360/ZB2005-35-6-506\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"采用新的样品制备方法和气-固自由扩散的实验方式, 使用漫反射傅立叶转换红外光谱原位反应器, 结合离子色谱、X-射线光电子能谱、扫描电子显微镜等分析方法, 研究了NO 2 在NaCl表面的非均相反应. 研究表明反应不只是发生在颗粒物表面, 体相也参与了反应; 颗粒物表面的活性点对反应起决定作用, 同时测定了反应级数为二级, 反应摄取系数为(1.54±0.70)× 10NO −5 .\",\"PeriodicalId\":49128,\"journal\":{\"name\":\"Science in China. Series B, Chemistry\",\"volume\":\"22 1\",\"pages\":\"506-517\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2005-12-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science in China. Series B, Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1360/ZB2005-35-6-506\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science in China. Series B, Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1360/ZB2005-35-6-506","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
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