一种在水中快速、高效、绿色地将烷基卤化物/邻苯二甲酸酯转化为有机氧原的方法

IF 1.4 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Phosphorus, Sulfur, and Silicon and the Related Elements Pub Date : 2018-01-01 DOI:10.1080/10426507.2017.1370592

Mohammad Soleiman-Beigi , Issa Yavari , Fatemeh Sadeghizadeh

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引用次数: 3

摘要

在无催化剂条件下，以苯基卤化物、烯丙基卤化物和伯卤化物为原料，以单质硫和硒为原料，在水介质中一锅高效合成了二烷基二硫族化合物(S, Se)。并将此方法推广到在相同条件下由仲卤化物和叔卤化物制备三硫化物和三硒化物。在所有情况下，产品都可以在短的反应时间内获得良好的收率。

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查看原文本刊更多论文

A rapid, efficient and green procedure for transformation of alkyl halides/ tosylates to organochalcogens in water

A one-pot and efficient synthesis of dialkyl dichalcogenides (S, Se) in aqueous media under catalyst-free conditions using benzylic, allylic and primary halides with elemental sulfur and selenium has been developed. Also, this procedure was extended to preparation of trisulfides and triselenides from secondary and tertiary halides in same condition. In all cases, products can be obtained in good to excellent yield in short reactions time.

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来源期刊

Phosphorus, Sulfur, and Silicon and the Related Elements 化学-无机化学与核化学

CiteScore

2.60

自引率

7.70%

发文量

103

审稿时长

2.1 months

期刊介绍： Phosphorus, Sulfur, and Silicon and the Related Elements is a monthly publication intended to disseminate current trends and novel methods to those working in the broad and interdisciplinary field of heteroatom chemistry.