单核铜络合物之字形链降解染料的研究

Fatma Darkbira, O. Nehar, Fatima Zohra Chiboub Fellah, T. Roisnel, A. Chiboub Fellah
{"title":"单核铜络合物之字形链降解染料的研究","authors":"Fatma Darkbira, O. Nehar, Fatima Zohra Chiboub Fellah, T. Roisnel, A. Chiboub Fellah","doi":"10.4028/p-kx6jk5","DOIUrl":null,"url":null,"abstract":"The titled mononuclear complex [Cu (L)] with the formally tetradentate schiff base ligand, [N,N’-bis (2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropan-2-ol] has been synthesized and characterized using IR spectroscopy and elemental analysis. Crystal structure has been determined by XRD which reveals the pseudo octahedral complex geometry and the use of hydroxo bridges between two neighbor units to form a 1D coordination polymer. The use of this complex as a catalyst for the degradation of two textile dyes, in the presence of the appropriate amount of H2O2 and a UV light source has given very good results with yields exceeding 98% after 50 minutes.","PeriodicalId":50368,"journal":{"name":"Industrial and Engineering Chemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2023-05-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Study of the Degradation of Dyes by a Mononuclear Copper Complex Forming a Zigzag Chain\",\"authors\":\"Fatma Darkbira, O. Nehar, Fatima Zohra Chiboub Fellah, T. Roisnel, A. Chiboub Fellah\",\"doi\":\"10.4028/p-kx6jk5\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The titled mononuclear complex [Cu (L)] with the formally tetradentate schiff base ligand, [N,N’-bis (2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropan-2-ol] has been synthesized and characterized using IR spectroscopy and elemental analysis. Crystal structure has been determined by XRD which reveals the pseudo octahedral complex geometry and the use of hydroxo bridges between two neighbor units to form a 1D coordination polymer. The use of this complex as a catalyst for the degradation of two textile dyes, in the presence of the appropriate amount of H2O2 and a UV light source has given very good results with yields exceeding 98% after 50 minutes.\",\"PeriodicalId\":50368,\"journal\":{\"name\":\"Industrial and Engineering Chemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Industrial and Engineering Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4028/p-kx6jk5\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Industrial and Engineering Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4028/p-kx6jk5","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

合成了具有四齿席夫碱配体[N,N ' -双(2-羟基-3-甲氧基苄基)-1,3-二氨基丙烯-2-醇]的单核配合物[Cu (L)],并用红外光谱和元素分析对其进行了表征。通过x射线衍射(XRD)测定了其晶体结构,揭示了伪八面体配合物的几何形状,并利用两个相邻单元之间的羟基桥形成了一维配位聚合物。用该络合物作为催化剂,在适量的H2O2和紫外光源的存在下,降解两种纺织染料,50分钟后收率超过98%,效果非常好。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study of the Degradation of Dyes by a Mononuclear Copper Complex Forming a Zigzag Chain
The titled mononuclear complex [Cu (L)] with the formally tetradentate schiff base ligand, [N,N’-bis (2-hydroxy-3-methoxybenzylidene)-1,3-diaminopropan-2-ol] has been synthesized and characterized using IR spectroscopy and elemental analysis. Crystal structure has been determined by XRD which reveals the pseudo octahedral complex geometry and the use of hydroxo bridges between two neighbor units to form a 1D coordination polymer. The use of this complex as a catalyst for the degradation of two textile dyes, in the presence of the appropriate amount of H2O2 and a UV light source has given very good results with yields exceeding 98% after 50 minutes.
求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信