{"title":"高能多硝基六氮唑烷衍生物的设计、合成和性能研究进展：改进 CL-20 类似物","authors":"Vladimir V. Parakhin, Gennady A. Smirnov","doi":"10.1016/j.fpc.2023.05.006","DOIUrl":null,"url":null,"abstract":"<div><p>In order to discover of high-energy materials with characteristics that surpass modern benchmarks, it is necessary to study the widest range of potential structures. The design of energetic compounds using high-nitrogen cage scaffolds provides new opportunities. One of the promising representatives of polycyclic multinitragen cages is the hexaazaisowurtzitane, since the most powerful explosive CL-20 is based on it. In recent years, the synthesis of CL-20 analogues has been actively developed. This review presents progress in the synthesis, performance and study of the structure-property relationship for energetic polynitro hexaazaisowurtzitanes over the past decade.</p></div>","PeriodicalId":100531,"journal":{"name":"FirePhysChem","volume":"4 1","pages":"Pages 21-33"},"PeriodicalIF":0.0000,"publicationDate":"2023-05-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2667134423000317/pdfft?md5=f0b981ce4869f4e2cb06666b7c0c7581&pid=1-s2.0-S2667134423000317-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Research progress on design, synthesis and performance of energetic polynitro hexaazaisowurtzitane derivatives: Towards improved CL-20 analogues\",\"authors\":\"Vladimir V. Parakhin, Gennady A. Smirnov\",\"doi\":\"10.1016/j.fpc.2023.05.006\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In order to discover of high-energy materials with characteristics that surpass modern benchmarks, it is necessary to study the widest range of potential structures. The design of energetic compounds using high-nitrogen cage scaffolds provides new opportunities. One of the promising representatives of polycyclic multinitragen cages is the hexaazaisowurtzitane, since the most powerful explosive CL-20 is based on it. In recent years, the synthesis of CL-20 analogues has been actively developed. This review presents progress in the synthesis, performance and study of the structure-property relationship for energetic polynitro hexaazaisowurtzitanes over the past decade.</p></div>\",\"PeriodicalId\":100531,\"journal\":{\"name\":\"FirePhysChem\",\"volume\":\"4 1\",\"pages\":\"Pages 21-33\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2023-05-25\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2667134423000317/pdfft?md5=f0b981ce4869f4e2cb06666b7c0c7581&pid=1-s2.0-S2667134423000317-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"FirePhysChem\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2667134423000317\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"FirePhysChem","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2667134423000317","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Research progress on design, synthesis and performance of energetic polynitro hexaazaisowurtzitane derivatives: Towards improved CL-20 analogues
In order to discover of high-energy materials with characteristics that surpass modern benchmarks, it is necessary to study the widest range of potential structures. The design of energetic compounds using high-nitrogen cage scaffolds provides new opportunities. One of the promising representatives of polycyclic multinitragen cages is the hexaazaisowurtzitane, since the most powerful explosive CL-20 is based on it. In recent years, the synthesis of CL-20 analogues has been actively developed. This review presents progress in the synthesis, performance and study of the structure-property relationship for energetic polynitro hexaazaisowurtzitanes over the past decade.
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