{"title":"醋酸乙酯提取物富集印楝生物柴油对铜的缓蚀作用","authors":"S. Iyyappan, P. Kannan, K. V. Kumar, V. Nagarajan","doi":"10.37896/pd91.3/9144","DOIUrl":null,"url":null,"abstract":"Neem biodiesel is enriched with antioxidant Piper nigrum ethyl acetate extract as a corrosion inhibitor for copper metal surface. The corrosion rate and corrosion inhibition efficiency at different acid values and temperature were evaluated and analysed. Notably, ASTM D130 evaluation reveals 98.0% corrosion inhibition efficiency in biodiesel. Impulsive adsorption of inhibitors on the metal surface was substantiated by negative free energy and heat of adsorption values. SEM surface morphological recordings were employed to study the surface changes of copper subjected for corrosion inhibition studies that revealed the protective nature of the inhibitor. Engine performance evaluations are found to be on par with the results of neem biodiesel alone and conventional diesel itself. Based on the above results, a new environmental-harmless corrosion inhibitor for copper corrosion in biodiesel is unearthed for practical purpose. Hence, this enriched biodiesel can be used as an alternative fuel that not only has good fuel value but also corrosion inhibition.","PeriodicalId":20006,"journal":{"name":"Periodico Di Mineralogia","volume":"1 1","pages":""},"PeriodicalIF":1.2000,"publicationDate":"2022-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Enriched Neem Biodiesel With Piper Nigrum Ethyl Acetate Extract For Corrosion Inhibition Of Copper\",\"authors\":\"S. Iyyappan, P. Kannan, K. V. Kumar, V. Nagarajan\",\"doi\":\"10.37896/pd91.3/9144\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Neem biodiesel is enriched with antioxidant Piper nigrum ethyl acetate extract as a corrosion inhibitor for copper metal surface. The corrosion rate and corrosion inhibition efficiency at different acid values and temperature were evaluated and analysed. Notably, ASTM D130 evaluation reveals 98.0% corrosion inhibition efficiency in biodiesel. Impulsive adsorption of inhibitors on the metal surface was substantiated by negative free energy and heat of adsorption values. SEM surface morphological recordings were employed to study the surface changes of copper subjected for corrosion inhibition studies that revealed the protective nature of the inhibitor. Engine performance evaluations are found to be on par with the results of neem biodiesel alone and conventional diesel itself. Based on the above results, a new environmental-harmless corrosion inhibitor for copper corrosion in biodiesel is unearthed for practical purpose. Hence, this enriched biodiesel can be used as an alternative fuel that not only has good fuel value but also corrosion inhibition.\",\"PeriodicalId\":20006,\"journal\":{\"name\":\"Periodico Di Mineralogia\",\"volume\":\"1 1\",\"pages\":\"\"},\"PeriodicalIF\":1.2000,\"publicationDate\":\"2022-04-02\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Periodico Di Mineralogia\",\"FirstCategoryId\":\"89\",\"ListUrlMain\":\"https://doi.org/10.37896/pd91.3/9144\",\"RegionNum\":4,\"RegionCategory\":\"地球科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"GEOCHEMISTRY & GEOPHYSICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Periodico Di Mineralogia","FirstCategoryId":"89","ListUrlMain":"https://doi.org/10.37896/pd91.3/9144","RegionNum":4,"RegionCategory":"地球科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"GEOCHEMISTRY & GEOPHYSICS","Score":null,"Total":0}
Enriched Neem Biodiesel With Piper Nigrum Ethyl Acetate Extract For Corrosion Inhibition Of Copper
Neem biodiesel is enriched with antioxidant Piper nigrum ethyl acetate extract as a corrosion inhibitor for copper metal surface. The corrosion rate and corrosion inhibition efficiency at different acid values and temperature were evaluated and analysed. Notably, ASTM D130 evaluation reveals 98.0% corrosion inhibition efficiency in biodiesel. Impulsive adsorption of inhibitors on the metal surface was substantiated by negative free energy and heat of adsorption values. SEM surface morphological recordings were employed to study the surface changes of copper subjected for corrosion inhibition studies that revealed the protective nature of the inhibitor. Engine performance evaluations are found to be on par with the results of neem biodiesel alone and conventional diesel itself. Based on the above results, a new environmental-harmless corrosion inhibitor for copper corrosion in biodiesel is unearthed for practical purpose. Hence, this enriched biodiesel can be used as an alternative fuel that not only has good fuel value but also corrosion inhibition.
期刊介绍:
Periodico di Mineralogia is an international peer-reviewed Open Access journal publishing Research Articles, Letters and Reviews in Mineralogy, Crystallography, Geochemistry, Ore Deposits, Petrology, Volcanology and applied topics on Environment, Archaeometry and Cultural Heritage. The journal aims at encouraging scientists to publish their experimental and theoretical results in as much detail as possible. Accordingly, there is no restriction on article length. Additional data may be hosted on the web sites as Supplementary Information. The journal does not have article submission and processing charges. Colour is free of charges both on line and printed and no Open Access fees are requested. Short publication time is assured.
Periodico di Mineralogia is property of Sapienza Università di Roma and is published, both online and printed, three times a year.