高矫顽力/高荧光杂化纳米结构的研制

D. Rawat, R. Singh
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引用次数: 0

摘要

重点研究了可同时包含多种功能的多功能核壳材料的前景。为了将铁磁核和半导体壳结合的核-壳纳米结构(CS-Ns)组装成具有可塑荧光和磁性的单一材料,种子介导水生长技术得到了蓬勃发展。SrFe12O19/CdS CS-Ns的设计是为了满足单个单元的磁荧光特性要求。采用XRD、VSM和光致发光光谱(PL)等表征技术对合成的CS-Ns进行了分析。XRD谱图证实了CS-Ns是纯相形成的。PL结果表明,CS-Ns遵循CdS壳层的发射谱线。CS-Ns的形成导致了更好的粒径分布。在VSM分析中观察到,由于覆盖在磁芯上的半导体壳层,磁滞回线的饱和比裸磁芯的饱和衰减了许多倍。总的来说,这些结果彼此吻合得很好。由于SrFe12O19的永磁性(1000°C),这些CS-Ns被用于磁选过程,其中铁磁核有助于磁操作,荧光壳有助于检测分离实体的路径。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Development of High Coercivity/High Fluorescence Hybrid nanostructures
The study concentrated on the prospects of multifunctional core-shell that can incorporate multiple functions simultaneously. For the sharp and precise assembling of core-shell nanostructures (CS-Ns) combining ferromagnetic-core and semiconducting-shell into a single material with mouldable fluorescence and magnetic features, the seed-mediated aqueous growth technique was flourished. SrFe12O19/CdS CS-Ns were designed to gratify the requirement of magneto-fluorescent features in a solo unit. Characterization techniques such as XRD, VSM and photoluminescence spectroscopy (PL) was used to analyze the as-synthesized CS-Ns. XRD spectra confirm the CS-Ns formation with the pure phase. PL results show that the CS-Ns follow the emission profile of the CdS shell. CS-Ns formation leads to a much better particle size distribution. In VSM analysis, it was observed that the saturation of the hysteresis loop is decayed many times as that of the bare core because of the semiconducting shell covering over the core. Altogether the results were in good agreement with one another. Because of the permanent magnetic nature of SrFe12O19 (1000°C), these CS-Ns are used in the magnetic separation process, where the ferromagnetic core aids in magnetic manipulation, and the fluorescent shell aids in detecting the path of the separated entity.
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CiteScore
2.40
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