{"title":"红酶敏化重氮化合物光解的基质效应","authors":"H. Böttcher, J. Marx, F.W. Müller, U. Papendieck","doi":"10.1016/0144-2880(85)90032-6","DOIUrl":null,"url":null,"abstract":"<div><p>Investigations have been made on erythrosine sensitized photolysis of 4-diethylaminobenzene diazonium salt <strong>1</strong> and 2-diazo-1-oxo-1,2-dihydronaphthalene <strong>2</strong> in polymeric binders of different glass transition temperatures (T<sub><em>g</em></sub> 30–185°C). In the case of <strong>1</strong> the efficiency of photolysis as well as the quenching of direct and delayed fluorescence increase with decreasing T<sub><em>g</em></sub>; in the case of <strong>2</strong>, however, they increase with increasing T<sub><em>g</em></sub>. The addition of plasticizers causes analogous effects. It is assumed that the sensitization of <strong>1</strong> occurs preferentially from the S<sub>1</sub>-state, whilst in case of <strong>2</strong> it is from the T<sub>1</sub>-state of erythrosine. Probability calculations reveal that the effective concentrations of the reactants within the critical radius of electron transfer are low, accounting for the low efficiency of the sensitized photolysis.</p></div>","PeriodicalId":101036,"journal":{"name":"Polymer Photochemistry","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"1985-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/0144-2880(85)90032-6","citationCount":"2","resultStr":"{\"title\":\"Matrix effects in erythrosine sensitized photolysis of diazo compounds\",\"authors\":\"H. Böttcher, J. Marx, F.W. Müller, U. Papendieck\",\"doi\":\"10.1016/0144-2880(85)90032-6\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Investigations have been made on erythrosine sensitized photolysis of 4-diethylaminobenzene diazonium salt <strong>1</strong> and 2-diazo-1-oxo-1,2-dihydronaphthalene <strong>2</strong> in polymeric binders of different glass transition temperatures (T<sub><em>g</em></sub> 30–185°C). In the case of <strong>1</strong> the efficiency of photolysis as well as the quenching of direct and delayed fluorescence increase with decreasing T<sub><em>g</em></sub>; in the case of <strong>2</strong>, however, they increase with increasing T<sub><em>g</em></sub>. The addition of plasticizers causes analogous effects. It is assumed that the sensitization of <strong>1</strong> occurs preferentially from the S<sub>1</sub>-state, whilst in case of <strong>2</strong> it is from the T<sub>1</sub>-state of erythrosine. Probability calculations reveal that the effective concentrations of the reactants within the critical radius of electron transfer are low, accounting for the low efficiency of the sensitized photolysis.</p></div>\",\"PeriodicalId\":101036,\"journal\":{\"name\":\"Polymer Photochemistry\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1985-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/0144-2880(85)90032-6\",\"citationCount\":\"2\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Polymer Photochemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/0144288085900326\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Polymer Photochemistry","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/0144288085900326","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Matrix effects in erythrosine sensitized photolysis of diazo compounds
Investigations have been made on erythrosine sensitized photolysis of 4-diethylaminobenzene diazonium salt 1 and 2-diazo-1-oxo-1,2-dihydronaphthalene 2 in polymeric binders of different glass transition temperatures (Tg 30–185°C). In the case of 1 the efficiency of photolysis as well as the quenching of direct and delayed fluorescence increase with decreasing Tg; in the case of 2, however, they increase with increasing Tg. The addition of plasticizers causes analogous effects. It is assumed that the sensitization of 1 occurs preferentially from the S1-state, whilst in case of 2 it is from the T1-state of erythrosine. Probability calculations reveal that the effective concentrations of the reactants within the critical radius of electron transfer are low, accounting for the low efficiency of the sensitized photolysis.
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