降冰片烯衍生物的多孔聚合物

PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS: ICAM 2019 Pub Date : 2019-10-29 DOI:10.1063/1.5130360

D. Alentiev, M. Bermeshev

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引用次数: 1

摘要

本文介绍了以降冰片烯衍生物为原料制备的多孔高分子材料。到目前为止，聚降冰片烯具有微孔或中孔和大表面积的三种类型。第一个是含有me3si的加成聚降冰片烯基团。这些聚合物是微孔的，具有高达800 m2/g的布鲁诺尔-埃米特-泰勒(BET)表面积。第二类包括聚降冰片烯，其侧聚合物链上有碳环。目前报道的多孔材料只有聚双环戊二烯。第三类包括基于双功能降冰片烯的聚合物。这些聚合物具有可调的多孔特性和高达1000 m2/g的大BET表面积。本文介绍了以降冰片烯衍生物为原料制备的多孔高分子材料。到目前为止，聚降冰片烯具有微孔或中孔和大表面积的三种类型。第一个是含有me3si的加成聚降冰片烯基团。这些聚合物是微孔的，具有高达800 m2/g的布鲁诺尔-埃米特-泰勒(BET)表面积。第二类包括聚降冰片烯，其侧聚合物链上有碳环。目前报道的多孔材料只有聚双环戊二烯。第三类包括基于双功能降冰片烯的聚合物。这些聚合物具有可调的多孔特性和高达1000 m2/g的大BET表面积。

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Porous polymers from norbornene derivatives

In the paper porous polymeric materials recently obtained from norbornene derivatives are presented. Up to now three groups of polynorbornenes exhibited the presence of micro-either mesopores and large surface area are considered. The first one is the group of Me3Si-containing addition polynorbornenes. These polymers are microporous and possess Brunauer-Emmett-Teller (BET) surface area up to 800 m2/g. The second group includes polynorbornenes with carbocycles in the side polymer chains. Up to now, only polydicyclopentadiene is reported as porous material from this group. The third group includes polymers based on bifunctional norbornenes. These polymers have demonstrated tunable porous properties and large BET surface area up to 1000 m2/g.In the paper porous polymeric materials recently obtained from norbornene derivatives are presented. Up to now three groups of polynorbornenes exhibited the presence of micro-either mesopores and large surface area are considered. The first one is the group of Me3Si-containing addition polynorbornenes. These polymers are microporous and possess Brunauer-Emmett-Teller (BET) surface area up to 800 m2/g. The second group includes polynorbornenes with carbocycles in the side polymer chains. Up to now, only polydicyclopentadiene is reported as porous material from this group. The third group includes polymers based on bifunctional norbornenes. These polymers have demonstrated tunable porous properties and large BET surface area up to 1000 m2/g.

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PROCEEDINGS OF THE INTERNATIONAL CONFERENCE ON ADVANCED MATERIALS: ICAM 2019

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