用俄歇电子能谱和FE-SEM对镀黄铜钢丝与橡胶胶料的粘接界面随湿度时效时间的微观表征

G. Jeon
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引用次数: 0

摘要

采用俄歇电子能谱和FE-SEM等深度分析方法,研究了镀黄铜钢丝绳与橡胶胶料黏附试样的湿度时效时间对黏附界面相的影响。结果表明,随着黏附试样湿度老化时间的延长,黏附试样湿度老化时间对黏附界面硫化铜和氧化锌的形成、生长和变质起主要作用。FE-SEM分析显示,固化后的黏附界面呈球形,湿老化后的黏附界面呈针状。湿老化处理下黏附试样的黏附稳定性可能与湿老化过程中抑制硫化铜的过度生长和抑制脱锌有关。版权所有©2018 VBRI出版社。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
On characterizing microscopically the adhesion interphases with humidity aging time for the adhesion between brass-plated steel cords and rubber compounds by Auger Electron Spectroscopy and FE-SEM
The effect of humidity aging time of adhesion samples made up of brass-plated steel cord and rubber compound on the adhesion interphase was studied by the depth profiling of Auger electron spectroscopy and FE-SEM. It was shown that humidity aging time of adhesion samples played major role of formation, growth and deterioration of copper sulfide and zinc oxide at the adhesion interphase with increased humidity aging time of adhesion samples. The adhesion interphase of adhesion sample after cure appeared the spherical shape whereas that after humidity aging treatment appeared the needle-like shape from FE-SEM analyses. The adhesion stability of adhesion samples against humidity aging treatment may be related to the suppression of the excessive growth of copper sulfide and the inhibition of dezincification during humidity aging time. Copyright © 2018 VBRI Press.
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