{"title":"对电解系统有效的一般关系","authors":"A. Michałowska-Kaczmarczyk, T. Michałowski","doi":"10.4236/JASMI.2015.54009","DOIUrl":null,"url":null,"abstract":"A simple general relation P = Q + R + 1 between the number P of kinds of species, the number Q of charge and elemental/core balances and the number R of independent equilibrium constants is deduced, and its validity is confirmed for non-redox and redox electrolytic systems, of different degree of complexity.","PeriodicalId":14932,"journal":{"name":"Journal of Analytical Sciences, Methods and Instrumentation","volume":"6 1","pages":"74-85"},"PeriodicalIF":0.0000,"publicationDate":"2015-12-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"7","resultStr":"{\"title\":\"General Relation Valid for Electrolytic Systems\",\"authors\":\"A. Michałowska-Kaczmarczyk, T. Michałowski\",\"doi\":\"10.4236/JASMI.2015.54009\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"A simple general relation P = Q + R + 1 between the number P of kinds of species, the number Q of charge and elemental/core balances and the number R of independent equilibrium constants is deduced, and its validity is confirmed for non-redox and redox electrolytic systems, of different degree of complexity.\",\"PeriodicalId\":14932,\"journal\":{\"name\":\"Journal of Analytical Sciences, Methods and Instrumentation\",\"volume\":\"6 1\",\"pages\":\"74-85\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2015-12-14\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Analytical Sciences, Methods and Instrumentation\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.4236/JASMI.2015.54009\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Analytical Sciences, Methods and Instrumentation","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.4236/JASMI.2015.54009","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 7
摘要
推导出物质种类数P、电荷数Q和元素/核心平衡数Q与独立平衡常数数R之间的简单一般关系P = Q + R + 1，并在不同复杂程度的非氧化还原和氧化还原电解体系中证实了其有效性。
A simple general relation P = Q + R + 1 between the number P of kinds of species, the number Q of charge and elemental/core balances and the number R of independent equilibrium constants is deduced, and its validity is confirmed for non-redox and redox electrolytic systems, of different degree of complexity.
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