Xin Yuan , Jie Liu , Hao Lv , Long-Zhou Qin , Xiu Duan , Jian Wang , Meng-Yu Wu , Beining Chen , Jiang-Kai Qiu , Kai Guo
{"title":"可见光通过远程杂芳基迁移诱导未活化烯烃的选择性烷基磺化反应","authors":"Xin Yuan , Jie Liu , Hao Lv , Long-Zhou Qin , Xiu Duan , Jian Wang , Meng-Yu Wu , Beining Chen , Jiang-Kai Qiu , Kai Guo","doi":"10.1016/j.gresc.2023.03.002","DOIUrl":null,"url":null,"abstract":"<div><p>Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO<sup><strong>.</strong></sup> (SO<sub>2</sub>)<sub>2</sub> and thianthrenium salts <em>via</em> a distal heteroaryl migration process has been developed, which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds. These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions, followed by distal heteroaryl migration. This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles.</p></div>","PeriodicalId":12794,"journal":{"name":"Green Synthesis and Catalysis","volume":"5 2","pages":"Pages 126-130"},"PeriodicalIF":0.0000,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2666554923000297/pdfft?md5=d4e55edbc8f0e277e19a185668202195&pid=1-s2.0-S2666554923000297-main.pdf","citationCount":"0","resultStr":"{\"title\":\"Visible-light-induced selective alkylsulfonylation of unactivated alkenes via remote heteroaryl migrations\",\"authors\":\"Xin Yuan , Jie Liu , Hao Lv , Long-Zhou Qin , Xiu Duan , Jian Wang , Meng-Yu Wu , Beining Chen , Jiang-Kai Qiu , Kai Guo\",\"doi\":\"10.1016/j.gresc.2023.03.002\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO<sup><strong>.</strong></sup> (SO<sub>2</sub>)<sub>2</sub> and thianthrenium salts <em>via</em> a distal heteroaryl migration process has been developed, which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds. These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions, followed by distal heteroaryl migration. This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles.</p></div>\",\"PeriodicalId\":12794,\"journal\":{\"name\":\"Green Synthesis and Catalysis\",\"volume\":\"5 2\",\"pages\":\"Pages 126-130\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-05-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://www.sciencedirect.com/science/article/pii/S2666554923000297/pdfft?md5=d4e55edbc8f0e277e19a185668202195&pid=1-s2.0-S2666554923000297-main.pdf\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Green Synthesis and Catalysis\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S2666554923000297\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Green Synthesis and Catalysis","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S2666554923000297","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Visible-light-induced selective alkylsulfonylation of unactivated alkenes via remote heteroaryl migrations
Photocatalyzed alkylsulfonylation of unactivated alkenes using DABCO. (SO2)2 and thianthrenium salts via a distal heteroaryl migration process has been developed, which provides a new means of synthesizing a variety of valuable alkylsulfonyl-substituted compounds. These alkylsulfonyl radicals couple with unactivated alkenes to undergo efficient intermolecular reactions, followed by distal heteroaryl migration. This mild catalytic method is tolerant of functional groups and affords medicinally relevant alkylsulfonylated heterocycles.
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