用介观概念解释磁性金属碳介观复合材料的合成特性

Kodolov Vi
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引用次数: 1

摘要

应用电荷量子化、相相干、干涉和湮灭等概念研究了介粒子修饰反应的机理。从介观理论的观点出发,讨论了在修饰反应中负电荷量子干扰下共价键的形成。提出了氧化还原过程中正负电荷量子相互作用湮灭可能性的假设。磁性金属碳介观复合材料的合成(如初始金属碳介观复合材料)是在金属氧化物微观颗粒与聚乙烯醇大分子研磨的基础上,通过机械化学方法实现的。得到了铜- 1,3 μB和镍- 1,8 μB原子磁矩的铜或镍碳介孔复合材料。对含p、d元素的化合物修饰铜、镍碳介粒的过程进行了分析实例研究。在其中间使用聚乙烯多胺、碘化铵、聚磷酸铵(APP)、二氧化硅(sio2)、氧化铝、氧化铁、氧化镍和氧化铜等物质。注意到红牛过程伴随着金属原子磁矩的增长,这可以用湮灭现象导致的高能电子位移来解释。提出了关于氧化还原过程中湮灭和干涉两种现象传递的假设。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
The Explanation of Magnetic Metal Carbon Mesocomposites Synthesis Peculiarities by Means of Mesoscopics Notions
Mechanism of mesoparticles modification reactions are considered with the application of such notions as charges quantization, phase coherence, interference and annihilation. On the base of theoretical Mesoscopics ideas the formation of covalent bonds because of the interference of negative charges quants in modification reactions is discussed. The hypothesis about possibility of annihilation at the interaction of positive and negative charges quants in redox processes is presented. The magnetic metal carbon mesoscopic composites synthesis (for example, initial metal carbon Mesocomposites) is realized by mechanochemical method at the grinding of metal oxides microscopic particles with polyvinyl alcohol macromolecules. Then in the result the Copper or Nickel Carbon mesocomposites which have the following atomic magnetic moments: for Copper – 1,3 μB, for Nickel – 1,8 μB are obtained. The investigations are carried out on the analysis examples of processes of Copper and Nickel Carbon mesoparticles modification by the compounds containing p, d elements. In the middle of its such substances as polyethylene polyamine, ammonium iodide, ammonium polyphosphate (APP), silica (SiO 2 ), aluminum oxide, iron oxide, nickel oxide and copper oxide are used. It’s noted that the red ox processes are accompanied by the metal atomic magnetic moments growth, that is explained by the electron shift on high energetic levels because of the annihilation phenomenon. The hypothesis concerning to the passing of two phenomena (annihilation and interference) at redox processes is proposed.
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