电化学合成高铁酸钾的研究

Chen Jian-jun
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摘要

在膜电池中,以金属铁为阳极,铂为阴极,电解13.5 mol·dm~(-3) KOH溶液,进行了高铁酸钾的电化学合成。最佳合成温度为30℃左右。电流密度约为0.5 mA/cm~2。目前在13.5 mol·dm~(-3) KOH溶液中合成效率为58.7%。充电电压在1.92 ~(1.83)之间变化电化学合成时间约2 ~ 3小时。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Study on electrochemical synthesis of potassium ferrate
The electrochemical synthesis of potassium ferrate was carried out in membrane cell with metal iron as anode and platinum as cathode in electrolysis of 13.5 mol·dm~(-3) KOH solution.The optimum temperature of synthesis is about 30℃.Current density is about 0.5 mA/cm~2.The current efficiency of the synthesis in 13.5 mol·dm~(-3) KOH solution is 58.7%.Charging voltage was varied between 1.92 to (l.83 V).Electrochemical synthesis time is about 2 to 3 hours.
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