淀粉糊法制备麦麸生物质多孔气凝胶制备高潜热储温相变复合材料

IF 5.3 3区 工程技术 Q2 ENERGY & FUELS
Xiugui Zhang, Mingyang Dong, Junqing Shi, Qingqing Wang, Qufu Wei and Yibing Cai*, 
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引用次数: 5

摘要

为了提高在一些极端环境下的适用性,人们在载流子材料中加载相变材料(PCMs)进行了大量的研究工作。麦麸作为一种农林业废弃物和廉价生物质,经常被忽视和丢弃,进一步成为严重的环境威胁。在本工作中,设计了一种有效的、高价值的WB在复合PCMs领域的应用。首先,采用简洁高效的碱处理方法控制麦麸淀粉糊化程度,并将麦麸内组分缠结形成三维网络,然后通过冷冻干燥法制备碱麦麸气凝胶(awb)。将AWBs作为生物质载体,掺入聚乙二醇(PEG),制备了复合PCMs (AWBs-PEG)。研究了复合材料的形态结构、防泄漏性能、储热性能、热稳定性和温度调节性能。结果表明,AWBs具有良好的防渗漏性能和较高的PEG吸附率(高达86.2%)。AWBs-PEG的熔融焓值可达153.5 J/g,结晶焓值可达134.3 J/g。AWBs-PEG具有较好的热循环稳定性、热可靠性和温度调节能力。AWBs-PEG与温敏油墨的集成显示出令人兴奋的变色缓冲性能。它将为太阳能热能储存、热红外隐身、先进智能纺织品等研究领域提供创新方向。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Construction of Wheat Bran Biomass Porous Aerogel by Starch Pasting for Fabrication of Phase Change Composites with High Latent Heat Storage and Temperature Regulation

Construction of Wheat Bran Biomass Porous Aerogel by Starch Pasting for Fabrication of Phase Change Composites with High Latent Heat Storage and Temperature Regulation

In order to improve the applicability in some extreme environments, a large number of research efforts have been conducted using carrier materials loaded with phase-change materials (PCMs). Wheat bran (WB), a kind of agroforestry waste and inexpensive biomass, is often ignored and discarded and further becomes a serious environmental threat. In this work, an effective high-value utility of WB in the field of composite PCMs was designed. First, briefness and efficient alkali-treated methods were adopted to control the degree of starch gelatinization of WB and the components within WB were entangled to form a three-dimensional network, and then the alkali–wheat bran aerogels (AWBs) were obtained via freeze-drying method. The AWBs were utilized as biomass carriers to incorporate polyethylene glycol (PEG), and the composite PCMs (AWBs-PEG) were fabricated. The morphological structure and the properties of antileakage, thermal storage, thermal stability, and temperature regulation of the fabricated composite PCMs were studied. The results indicated that AWBs exhibited excellent performances including good antileakage and high PEG adsorption rate (up to 86.2%). The melting and crystallization enthalpy values of AWBs-PEG could reach 153.5 J/g and 134.3 J/g, respectively. It could also be found that AWBs-PEG possessed a superior thermal cycle stability, thermal reliability, and temperature regulation ability. The integration of AWBs-PEG with temperature sensitive ink demonstrated an exciting color-change buffering property. It would provide an innovative direction for solar thermal energy storage, thermal infrared stealth, advanced smart textiles, and other research fields.

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来源期刊
Energy & Fuels
Energy & Fuels 工程技术-工程:化工
CiteScore
9.20
自引率
13.20%
发文量
1101
审稿时长
2.1 months
期刊介绍: Energy & Fuels publishes reports of research in the technical area defined by the intersection of the disciplines of chemistry and chemical engineering and the application domain of non-nuclear energy and fuels. This includes research directed at the formation of, exploration for, and production of fossil fuels and biomass; the properties and structure or molecular composition of both raw fuels and refined products; the chemistry involved in the processing and utilization of fuels; fuel cells and their applications; and the analytical and instrumental techniques used in investigations of the foregoing areas.
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