Huiru Zhao, Qinghu Tang, Yi Wang, Tao Qi, Xin Wang
{"title":"pda功能化Ti4O7负载Pd纳米粒子作为甲酸电氧化的有效催化剂","authors":"Huiru Zhao, Qinghu Tang, Yi Wang, Tao Qi, Xin Wang","doi":"10.1149/2.0051409SSL","DOIUrl":null,"url":null,"abstract":"Pd catalysts supported on carbon black and Ti4O7 were prepared and used as electrocatalysts for formic acid electrooxidation. The structure and morphology were characterized by XRD and TEM. CV results show that Pd/Ti4O7 possesses a higher catalytic activity than Pd/C. XPS analyzes suggest that the higher content of metallic Pd caused by Ti4O7 contributes to the better catalytic performance. Based on the good electrocatalytic performance of Pd/Ti4O7, Pd catalyst supported on PDDA-functionalized Ti4O7 was prepared and exhibited a better catalytic activity. The improvement results from the further increase of metallic Pd content due to the presence of PDDA. (C) 2014 The Electrochemical Society. All rights reserved.","PeriodicalId":11423,"journal":{"name":"ECS Solid State Letters","volume":"7 1","pages":""},"PeriodicalIF":0.0000,"publicationDate":"2014-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"4","resultStr":"{\"title\":\"Pd Nanoparticles Supported on PDDA-Functionalized Ti4O7 as an Effective Catalyst for Formic Acid Electrooxidation\",\"authors\":\"Huiru Zhao, Qinghu Tang, Yi Wang, Tao Qi, Xin Wang\",\"doi\":\"10.1149/2.0051409SSL\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Pd catalysts supported on carbon black and Ti4O7 were prepared and used as electrocatalysts for formic acid electrooxidation. The structure and morphology were characterized by XRD and TEM. CV results show that Pd/Ti4O7 possesses a higher catalytic activity than Pd/C. XPS analyzes suggest that the higher content of metallic Pd caused by Ti4O7 contributes to the better catalytic performance. Based on the good electrocatalytic performance of Pd/Ti4O7, Pd catalyst supported on PDDA-functionalized Ti4O7 was prepared and exhibited a better catalytic activity. The improvement results from the further increase of metallic Pd content due to the presence of PDDA. (C) 2014 The Electrochemical Society. All rights reserved.\",\"PeriodicalId\":11423,\"journal\":{\"name\":\"ECS Solid State Letters\",\"volume\":\"7 1\",\"pages\":\"\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2014-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"4\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"ECS Solid State Letters\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1149/2.0051409SSL\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"ECS Solid State Letters","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1149/2.0051409SSL","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Pd Nanoparticles Supported on PDDA-Functionalized Ti4O7 as an Effective Catalyst for Formic Acid Electrooxidation
Pd catalysts supported on carbon black and Ti4O7 were prepared and used as electrocatalysts for formic acid electrooxidation. The structure and morphology were characterized by XRD and TEM. CV results show that Pd/Ti4O7 possesses a higher catalytic activity than Pd/C. XPS analyzes suggest that the higher content of metallic Pd caused by Ti4O7 contributes to the better catalytic performance. Based on the good electrocatalytic performance of Pd/Ti4O7, Pd catalyst supported on PDDA-functionalized Ti4O7 was prepared and exhibited a better catalytic activity. The improvement results from the further increase of metallic Pd content due to the presence of PDDA. (C) 2014 The Electrochemical Society. All rights reserved.
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