一种新型有效的铜催化卤化物胺化配体的设计与应用

IF 5.8 3区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Green Chemistry Letters and Reviews Pub Date : 2022-12-22 DOI:10.1080/17518253.2022.2147027

Lifang Wang, Xinhai Zhu, Zexuan Liang, Manna Huang, Y. Wan

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Design and application of a novel and effective ligand for the Cu-catalyzed amination of aryl halides in water

ABSTRACT An effective ligand for the Ullmann-type C–N coupling reaction in water has been obtained using a novel tactic, namely, introducing a third group into the ligand to both improve the ligand’s water solubility and enhance the ligand’s coordinating ability. Applying this method, we have developed an effective ligand for the Cu-catalyzed amination of aryl halides, in particular, for aryl chlorides in water. The substrate diversity of the catalyst system, relatively less time required (6–12 h), and water as the reaction solvent make it attractive in both academia and industry. GRAPHICAL ABSTRACT

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来源期刊

Green Chemistry Letters and Reviews CHEMISTRY, MULTIDISCIPLINARY-GREEN & SUSTAINABLE SCIENCE & TECHNOLOGY

CiteScore

9.10

自引率

3.00%

发文量

期刊介绍： Green Chemistry Letters and Reviews is an Open Access, peer-reviewed journal focused on rapid publication of innovative new syntheses and procedures that reduce or eliminate the use and generation of hazardous materials. Reviews of state-of-the-art green chemistry technologies are also included within the journal''s scope. Green Chemistry Letters and Reviews is divided into three overlapping topic areas: research, education, and industrial implementation. The journal publishes both letters, which concisely communicate the most time-sensitive results, and reviews, which aid researchers in understanding the state of science on important green chemistry topics. Submissions are encouraged which apply the 12 principles of green chemistry to: -Green Chemistry Education- Synthetic Reaction Pathways- Research and Process Analytical Techniques- Separation and Purification Technologies- Renewable Feedstocks- Degradable Products