用于铝生产的阳极膏用量

IF 0.6 4区 材料科学 Q4 METALLURGY & METALLURGICAL ENGINEERING
A. Drizhenko, S. Datsyura, A. Yasinskiy
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引用次数: 0

摘要

在俄罗斯,由于阳极材料在铝的成本中所占的份额从8%到20%不等,大多数铝冶炼厂都配备了带有自焙阳极的电解槽,迫切需要降低阳极膏的消耗。要解决这一问题,必须确定阳极膏的需求量。铝厂所用的阳极膏用量计算方法精度较差。讨论了该方法的主要误差,指出了阳极膏消耗量计算的各个阶段,评价了计算的充分性,并提出了改进方法的建议。结果表明,一般情况下所考虑的方法能充分反映碳消耗过程,但最终计算结果可能与实际存在较大差异。为简化计算而取的常数,实际上在电解过程中可能会发生变化,从而导致最终计算结果发生显著变化。例如,将二氧化碳含量从0.45增加到0.5,将导致阳极膏消耗减少15.3 kg/tonAl。同时,我们知道阳极气体的组成随着阳极效应的发生而急剧变化:CO2分数降低,CO分数增加。在夏季,在较高的环境温度下,汽化沥青和阳极的比例随着表面温度的升高而升高。当后者变为0.25时,消耗量增加6.6 kg/tonAl。这同样适用于空气氧化。减压电池的数量可能随着碳消耗的增加而增加。有必要注意影响阳极质量的因素。错误选择的粒度分布或磨损的设备可能会显著降低阳极质量并导致碳消耗增加。为了适当地考虑一氧化碳形成的特殊性,有必要对计算进行调整。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Anode paste consumption for aluminum production
 In Russia, most aluminum smelters are equipped with cells with self-baking anodes featuring an urgent problem of lowering the anode paste consumption, since the share of anode materials in the cost of aluminum varies from 8 to 20 %. To solve this problem, it is necessary to determine the anode paste demand. The method for calculating the specific anode paste consumption used at aluminum smelters has a poor accuracy. The paper discusses the main errors of this method, shows the stages of anode paste consumption calculation, assesses the adequacy of calculations and gives recommendations for method improvement. It is shown that in general the considered method adequately reflects carbon consumption processes, but the final result of calculations may differ significantly from the actual one. The values taken constant to simplify the calculation, in fact, may vary during the electrolysis, which leads to a significant change in the final result of calculations. For example, an increase in the CO2 fraction from 0.45 to 0.5 leads to a decrease in the anode paste consumption by 15.3 kg/tonAl. At the same time, it is known that the composition of anode gases changes sharply as the anode effect occurs: the CO2 fraction decreases, and the CO fraction increases. In summer, at high ambient temperatures, the proportion of both vaporized pitch and anodes with an increased surface temperature rise. As the latter changes to 0.25, the consumption increases by 6.6 kg/tonAl. The same applies to air oxidation. The number of depressurized cells may increase with the subsequent increase in the carbon consumption. It is necessary to pay attention to factors affecting the anode quality. Incorrectly selected particle size distribution or worn equipment may significantly degrade the anode quality and lead to an increase in carbon consumption. It is necessary to make adjustments to the calculation in order to consider the peculiarities of carbon monoxide formation properly.
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来源期刊
Russian Journal of Non-Ferrous Metals
Russian Journal of Non-Ferrous Metals METALLURGY & METALLURGICAL ENGINEERING-
CiteScore
1.90
自引率
12.50%
发文量
59
审稿时长
3 months
期刊介绍: Russian Journal of Non-Ferrous Metals is a journal the main goal of which is to achieve new knowledge in the following topics: extraction metallurgy, hydro- and pirometallurgy, casting, plastic deformation, metallography and heat treatment, powder metallurgy and composites, self-propagating high-temperature synthesis, surface engineering and advanced protected coatings, environments, and energy capacity in non-ferrous metallurgy.
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