{"title":"人工分形界面上的催化反应:用“魔鬼梳”模拟","authors":"Pascal Mougin, Michel Pons, Jacques Villermaux","doi":"10.1016/S0923-0467(96)03104-1","DOIUrl":null,"url":null,"abstract":"<div><p>We have proposed the model of a 2-D fractal objects exhibiting an important contour length within a finite area. This structure offers a large internal interface can be used as a catalytic support. In the case of a single first-order reaction A → R at the interface, numerical simulations show evidence for a new diffusional regime due to the fractality of the support. In this regime, the rate of formation of product R no longer depends on the kinetic rate constant of the reaction.</p></div>","PeriodicalId":101226,"journal":{"name":"The Chemical Engineering Journal and the Biochemical Engineering Journal","volume":"64 1","pages":"Pages 63-68"},"PeriodicalIF":0.0000,"publicationDate":"1996-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/S0923-0467(96)03104-1","citationCount":"7","resultStr":"{\"title\":\"Catalytic reactions at an artificial fractal interface: Simulation with the ‘Devil's Comb’\",\"authors\":\"Pascal Mougin, Michel Pons, Jacques Villermaux\",\"doi\":\"10.1016/S0923-0467(96)03104-1\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>We have proposed the model of a 2-D fractal objects exhibiting an important contour length within a finite area. This structure offers a large internal interface can be used as a catalytic support. In the case of a single first-order reaction A → R at the interface, numerical simulations show evidence for a new diffusional regime due to the fractality of the support. In this regime, the rate of formation of product R no longer depends on the kinetic rate constant of the reaction.</p></div>\",\"PeriodicalId\":101226,\"journal\":{\"name\":\"The Chemical Engineering Journal and the Biochemical Engineering Journal\",\"volume\":\"64 1\",\"pages\":\"Pages 63-68\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"1996-10-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/S0923-0467(96)03104-1\",\"citationCount\":\"7\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"The Chemical Engineering Journal and the Biochemical Engineering Journal\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0923046796031041\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"The Chemical Engineering Journal and the Biochemical Engineering Journal","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0923046796031041","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Catalytic reactions at an artificial fractal interface: Simulation with the ‘Devil's Comb’
We have proposed the model of a 2-D fractal objects exhibiting an important contour length within a finite area. This structure offers a large internal interface can be used as a catalytic support. In the case of a single first-order reaction A → R at the interface, numerical simulations show evidence for a new diffusional regime due to the fractality of the support. In this regime, the rate of formation of product R no longer depends on the kinetic rate constant of the reaction.
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