亚伯拉罕溶剂化参数模型:修正的预测表达式溶质转移到聚二甲基硅氧烷基于更大的和化学多样化的数据集

Compounds Pub Date : 2023-02-20 DOI:10.3390/compounds3010017

Amy Zhou, Laine Longacre, Ramya Motati, W. Acree

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引用次数: 1

摘要

根据已发表的220多种不同化合物的实验数据，报告了有机溶质和无机气体从水和气相转移到聚二甲基硅氧烷涂层的最新Abraham模型相关性。导出的数学表达式将观察到的划分行为反算到残差的标准差范围内，分别为0.206和0.176个对数单位。

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Abraham Solvation Parameter Model: Revised Predictive Expressions for Solute Transfer into Polydimethylsiloxane Based on Much Larger and Chemically Diverse Datasets

Updated Abraham model correlations are reported for the transfer of organic solutes and inorganic gases to a polydimethylsiloxane coating from both water and the gas phase based on published experimental data for more than 220 different compounds. The derived mathematical expressions back-calculate the observed partitioning behavior to within standard deviations of the residuals of 0.206 and 0.176 log units, respectively.

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来源期刊

Compounds

CiteScore

2.30

自引率

0.00%

发文量