{"title":"高温铝熔体点燃 Al-ZnO 系统的反应行为","authors":"Panpan Guo, Rui Yang, Gang Chen, Jingcun Hao, Xuecai Zheng, Yutao Zhao","doi":"10.1007/s11665-023-08064-4","DOIUrl":null,"url":null,"abstract":"<div><p>In this work, a constant heat source, high-temperature Al melt, was used to fast ignite thermite reactions between Al and ZnO nanoparticles (ZnO<sub><i>np</i></sub>). The effect of initial temperatures (<i>T</i><sub>i</sub>) on reaction behavior was emphasized to reveal underlying mechanisms. The results indicate that there were two reaction modes dependent on <i>T</i><sub>i</sub>, i.e., boundary diffusion and thermal explosion. Specifically, when <i>T</i><sub>i</sub> = 900 °C, the diffusion-assisted nucleation mechanism enabled small amounts of Al<sub>2</sub>O<sub>3</sub> nanodispersions to form on Al powder surfaces. As <i>T</i><sub>i</sub> increased up to 1100 °C and above, self-sustaining combustion remarkably promoted the diffusion fluxes of Al and [O], resulting in almost instantaneous nucleation of Al<sub>2</sub>O<sub>3</sub> throughout the whole region. Moreover, although in situ Al<sub>2</sub>O<sub>3</sub> particles tend to sinter together under higher <i>T</i><sub>i</sub>, their limited growth could be attributed to evaporation and oxidization of the reduced [Zn] that consumed excess reaction enthalpy. Al<sub>2</sub>O<sub>3</sub> particles uniformly dispersed in the aluminum matrix have been obtained by remelting and diluting the master alloy reacted at 1100 °C.</p></div>","PeriodicalId":644,"journal":{"name":"Journal of Materials Engineering and Performance","volume":"33 4","pages":"1572 - 1576"},"PeriodicalIF":2.2000,"publicationDate":"2023-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Reaction Behaviors of Al-ZnO System Ignited by High-Temperature Al Melt\",\"authors\":\"Panpan Guo, Rui Yang, Gang Chen, Jingcun Hao, Xuecai Zheng, Yutao Zhao\",\"doi\":\"10.1007/s11665-023-08064-4\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>In this work, a constant heat source, high-temperature Al melt, was used to fast ignite thermite reactions between Al and ZnO nanoparticles (ZnO<sub><i>np</i></sub>). The effect of initial temperatures (<i>T</i><sub>i</sub>) on reaction behavior was emphasized to reveal underlying mechanisms. The results indicate that there were two reaction modes dependent on <i>T</i><sub>i</sub>, i.e., boundary diffusion and thermal explosion. Specifically, when <i>T</i><sub>i</sub> = 900 °C, the diffusion-assisted nucleation mechanism enabled small amounts of Al<sub>2</sub>O<sub>3</sub> nanodispersions to form on Al powder surfaces. As <i>T</i><sub>i</sub> increased up to 1100 °C and above, self-sustaining combustion remarkably promoted the diffusion fluxes of Al and [O], resulting in almost instantaneous nucleation of Al<sub>2</sub>O<sub>3</sub> throughout the whole region. Moreover, although in situ Al<sub>2</sub>O<sub>3</sub> particles tend to sinter together under higher <i>T</i><sub>i</sub>, their limited growth could be attributed to evaporation and oxidization of the reduced [Zn] that consumed excess reaction enthalpy. Al<sub>2</sub>O<sub>3</sub> particles uniformly dispersed in the aluminum matrix have been obtained by remelting and diluting the master alloy reacted at 1100 °C.</p></div>\",\"PeriodicalId\":644,\"journal\":{\"name\":\"Journal of Materials Engineering and Performance\",\"volume\":\"33 4\",\"pages\":\"1572 - 1576\"},\"PeriodicalIF\":2.2000,\"publicationDate\":\"2023-03-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Materials Engineering and Performance\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s11665-023-08064-4\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q3\",\"JCRName\":\"MATERIALS SCIENCE, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Materials Engineering and Performance","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s11665-023-08064-4","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q3","JCRName":"MATERIALS SCIENCE, MULTIDISCIPLINARY","Score":null,"Total":0}
引用次数: 0
摘要
在这项工作中,使用了高温铝熔体这一恒定热源来快速点燃铝和氧化锌纳米颗粒(ZnOnp)之间的热核反应。研究强调了初始温度(Ti)对反应行为的影响,以揭示其潜在机制。结果表明,有两种反应模式取决于 Ti,即边界扩散和热爆炸。具体来说,当 Ti = 900 ℃ 时,扩散辅助成核机制使少量 Al2O3 纳米分散体在铝粉表面形成。当 Ti 升高到 1100 ℃ 及以上时,自持燃烧显著促进了 Al 和 [O] 的扩散通量,导致 Al2O3 在整个区域几乎瞬间成核。此外,虽然原位 Al2O3 颗粒在较高的 Ti 温度下倾向于烧结在一起,但其有限的增长可能是由于还原[Zn]的蒸发和氧化消耗了过多的反应热焓。通过重熔和稀释在 1100 ℃ 下反应的母合金,可以获得均匀分布在铝基体中的 Al2O3 颗粒。
Reaction Behaviors of Al-ZnO System Ignited by High-Temperature Al Melt
In this work, a constant heat source, high-temperature Al melt, was used to fast ignite thermite reactions between Al and ZnO nanoparticles (ZnOnp). The effect of initial temperatures (Ti) on reaction behavior was emphasized to reveal underlying mechanisms. The results indicate that there were two reaction modes dependent on Ti, i.e., boundary diffusion and thermal explosion. Specifically, when Ti = 900 °C, the diffusion-assisted nucleation mechanism enabled small amounts of Al2O3 nanodispersions to form on Al powder surfaces. As Ti increased up to 1100 °C and above, self-sustaining combustion remarkably promoted the diffusion fluxes of Al and [O], resulting in almost instantaneous nucleation of Al2O3 throughout the whole region. Moreover, although in situ Al2O3 particles tend to sinter together under higher Ti, their limited growth could be attributed to evaporation and oxidization of the reduced [Zn] that consumed excess reaction enthalpy. Al2O3 particles uniformly dispersed in the aluminum matrix have been obtained by remelting and diluting the master alloy reacted at 1100 °C.
期刊介绍:
ASM International''s Journal of Materials Engineering and Performance focuses on solving day-to-day engineering challenges, particularly those involving components for larger systems. The journal presents a clear understanding of relationships between materials selection, processing, applications and performance.
The Journal of Materials Engineering covers all aspects of materials selection, design, processing, characterization and evaluation, including how to improve materials properties through processes and process control of casting, forming, heat treating, surface modification and coating, and fabrication.
Testing and characterization (including mechanical and physical tests, NDE, metallography, failure analysis, corrosion resistance, chemical analysis, surface characterization, and microanalysis of surfaces, features and fractures), and industrial performance measurement are also covered