一种新型(3,6)连接蚂蚁结构的Cd(II)配位聚合物的结构和发光性能

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2016-05-24 DOI:10.1080/15533174.2015.1136962

Zhuo-wen Fan, Long Li, K. Cui, Shuangbing Yang, Fusan Han

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引用次数: 2

摘要

Cd(NO3)2、H3btc和HBTA的溶剂热反应生成新的Cd(II)化合物(NH3)2[Cd3(btc)2(BTA)(DMA)]n (1 H3btc = 1,3,5-苯三羧酸，HBTA = 1,2,3-苯三唑，DMA = n, n ' -二甲基乙酰胺)。单晶x射线分析表明，1是基于苯并三唑控制的三核Cd(II)团簇的复杂三维(3D)框架，可以简化为(3,6)连接的蚁型拓扑网络。此外，还研究了该化合物在室温下的发光性能。

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Structure and Luminescent Property of a New Cd(II) Coordination Polymer With (3,6)-Connected ant Topology

Solvothermal reactions of Cd(NO3)2, H3btc, and HBTA afforded a new Cd(II) compound, namely (NH3)2[Cd3(btc)2(BTA)(DMA)]n (1 H3btc = 1,3,5-benzenetricarboxylic acid, HBTA = 1,2,3- benzenetriazole, DMA = N, N′-dimethylacetamide). Single-crystal X-ray analysis reveals that 1 is a complicated three-dimensional (3D) framework based on benzotriazole-controlled trinuclear Cd(II) clusters, which can be simplified into a (3,6)-connected ant-type topological network. Moreover, the luminescent properties of this compound were also investigated at room temperature.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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审稿时长

5 months