C. Peike, Lea Purschke, K. Weiß, Michael Kohl, M. Kempe
{"title":"光化学EVA变色的成因探讨","authors":"C. Peike, Lea Purschke, K. Weiß, Michael Kohl, M. Kempe","doi":"10.1109/PVSC.2013.6744447","DOIUrl":null,"url":null,"abstract":"The root cause of the photochemical ethylene vinyl acetate (EVA) discoloration in photovoltaic (PV) modules was investigated. Laminates containing EVA foils with a systematic variation of the additive formulation, i.e. the crosslinking agents, ultraviolet (UV) absorber, hindered amine light stabilizers and antioxidants, were subjected to UV aging. The influence of the additive combination on the photochemical aging of EVA was investigated by Raman spectroscopy, Fourier transform infrared spectroscopy and UV/visible spectroscopy. The amount of EVA discoloration was found to be strongly depending on the additive formation. An important impact of the antioxidant in terms of chromophore formation inhibition could be found. Surprisingly, the highly stabilized EVA foils showed higher discoloration rates as well as a more intense fluorescence background in the Raman spectra.","PeriodicalId":6350,"journal":{"name":"2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)","volume":"22 1","pages":"1579-1584"},"PeriodicalIF":0.0000,"publicationDate":"2013-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"36","resultStr":"{\"title\":\"Towards the origin of photochemical EVA discoloration\",\"authors\":\"C. Peike, Lea Purschke, K. Weiß, Michael Kohl, M. Kempe\",\"doi\":\"10.1109/PVSC.2013.6744447\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"The root cause of the photochemical ethylene vinyl acetate (EVA) discoloration in photovoltaic (PV) modules was investigated. Laminates containing EVA foils with a systematic variation of the additive formulation, i.e. the crosslinking agents, ultraviolet (UV) absorber, hindered amine light stabilizers and antioxidants, were subjected to UV aging. The influence of the additive combination on the photochemical aging of EVA was investigated by Raman spectroscopy, Fourier transform infrared spectroscopy and UV/visible spectroscopy. The amount of EVA discoloration was found to be strongly depending on the additive formation. An important impact of the antioxidant in terms of chromophore formation inhibition could be found. Surprisingly, the highly stabilized EVA foils showed higher discoloration rates as well as a more intense fluorescence background in the Raman spectra.\",\"PeriodicalId\":6350,\"journal\":{\"name\":\"2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)\",\"volume\":\"22 1\",\"pages\":\"1579-1584\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-06-16\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"36\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1109/PVSC.2013.6744447\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"2013 IEEE 39th Photovoltaic Specialists Conference (PVSC)","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1109/PVSC.2013.6744447","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Towards the origin of photochemical EVA discoloration
The root cause of the photochemical ethylene vinyl acetate (EVA) discoloration in photovoltaic (PV) modules was investigated. Laminates containing EVA foils with a systematic variation of the additive formulation, i.e. the crosslinking agents, ultraviolet (UV) absorber, hindered amine light stabilizers and antioxidants, were subjected to UV aging. The influence of the additive combination on the photochemical aging of EVA was investigated by Raman spectroscopy, Fourier transform infrared spectroscopy and UV/visible spectroscopy. The amount of EVA discoloration was found to be strongly depending on the additive formation. An important impact of the antioxidant in terms of chromophore formation inhibition could be found. Surprisingly, the highly stabilized EVA foils showed higher discoloration rates as well as a more intense fluorescence background in the Raman spectra.
求助内容：
应助结果提醒方式：
京公网安备 11010802042870号
