左旋海松酸与丙烯酸和乙二醇的加合物作为金属的酸腐蚀抑制剂

M. S. Pirguliyeva, A. Guliyev
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引用次数: 0

摘要

通过左旋海松酸与丙烯酸的二烯缩合反应,并对左旋海松酸进行乙二硫醇自由基加成,合成了加合物。通过元素分析、红外光谱和核磁共振光谱对这些加合物的组成和结构进行了鉴定。在酸性介质(硫酸溶液1H和5H)中,用重量法(测定C-3标号钢板试样的质量损失)测定了合成的二酸作为缓蚀剂的效率。分析了介质温度和所用化合物浓度对保护程度和缓蚀系数的影响。结果表明,温度升高会导致抑制剂的保护作用增强。请注意,抑制剂浓度的增加,虽然提高了保护程度,但并不那么明显。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
ADDUCTS OF LEVOPIMARIC ACID WITH ACRYLIC ACID AND ETHANEDITHIOL AS ACID CORROSION INHIBITORS OF METALS
The adducts were synthesized by means of diene condensation reaction of levopimaric acid with acrylic acid, and through carrying out the free radical addition of ethandithiol to levopimaric acid. The composition and structure of these adducts were identified through data of the elemental analysis, IR and PMR spectroscopy. The efficiency of the synthesized diacids as corrosion inhibitors was determined by means of the gravimetric method (on mass losses of a sample of steel plate of mark C-3) in an acidic medium (solutions of 1H and 5H of sulfuric acid). The influence of the medium temperature and concentration of the used compounds on the degree of protection and corrosion inhibition coefficient was analyzed. It found that rise in temperature results in the increase of protective effect of the inhibitor. Note that the increase of the inhibitor concentration, raising the degree of protection though, is not so noticeable.
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