{"title":"全合成印楝素昆虫防食剂的研究","authors":"A. Murai*","doi":"10.1081/TXR-120026917","DOIUrl":null,"url":null,"abstract":"Efficient construction of the respective right and left segments of azadirachtin is described. Furthermore, studies on the connection between both the segments are also mentioned; the Ireland‐Claisen rearrangement of Li‐enolate of the modelled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield.","PeriodicalId":17561,"journal":{"name":"Journal of Toxicology-toxin Reviews","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2003-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"5","resultStr":"{\"title\":\"Studies Aimed at the Total Synthesis of Azadirachtin as an Insect Antifeedant\",\"authors\":\"A. Murai*\",\"doi\":\"10.1081/TXR-120026917\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Efficient construction of the respective right and left segments of azadirachtin is described. Furthermore, studies on the connection between both the segments are also mentioned; the Ireland‐Claisen rearrangement of Li‐enolate of the modelled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield.\",\"PeriodicalId\":17561,\"journal\":{\"name\":\"Journal of Toxicology-toxin Reviews\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2003-01-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"5\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of Toxicology-toxin Reviews\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1081/TXR-120026917\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of Toxicology-toxin Reviews","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1081/TXR-120026917","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
Studies Aimed at the Total Synthesis of Azadirachtin as an Insect Antifeedant
Efficient construction of the respective right and left segments of azadirachtin is described. Furthermore, studies on the connection between both the segments are also mentioned; the Ireland‐Claisen rearrangement of Li‐enolate of the modelled ester with dichlorodimethylsilane in toluene afforded the desired limonoid framework stereoselectively in good yield.
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