{"title":"一种简单、高效的立体选择性全合成(−)-赛定胺","authors":"Saroja Nuguri , Laxminarayana Eppakayala , Naresh Kumar Vuppula , Prasad Kottapalli Rajasekhara","doi":"10.1016/j.ijcas.2013.07.004","DOIUrl":null,"url":null,"abstract":"<div><p>An asymmetric synthesis of the piperidine alkaloid (−)-sedridine isolated from Sedum acre, has been accomplished starting from <em>S</em>-malic acid as the chiral precursor employing Maruoka Keck allylation, azide nucleophillic substitution and ring closing metathesis as the key steps.</p></div>","PeriodicalId":100693,"journal":{"name":"International Journal of Chemical and Analytical Science","volume":"4 2","pages":"Pages 131-135"},"PeriodicalIF":0.0000,"publicationDate":"2013-06-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1016/j.ijcas.2013.07.004","citationCount":"3","resultStr":"{\"title\":\"A simple and efficient stereoselective total synthesis of (−)-sedridine\",\"authors\":\"Saroja Nuguri , Laxminarayana Eppakayala , Naresh Kumar Vuppula , Prasad Kottapalli Rajasekhara\",\"doi\":\"10.1016/j.ijcas.2013.07.004\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>An asymmetric synthesis of the piperidine alkaloid (−)-sedridine isolated from Sedum acre, has been accomplished starting from <em>S</em>-malic acid as the chiral precursor employing Maruoka Keck allylation, azide nucleophillic substitution and ring closing metathesis as the key steps.</p></div>\",\"PeriodicalId\":100693,\"journal\":{\"name\":\"International Journal of Chemical and Analytical Science\",\"volume\":\"4 2\",\"pages\":\"Pages 131-135\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2013-06-01\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"https://sci-hub-pdf.com/10.1016/j.ijcas.2013.07.004\",\"citationCount\":\"3\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"International Journal of Chemical and Analytical Science\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://www.sciencedirect.com/science/article/pii/S0976120913000302\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"International Journal of Chemical and Analytical Science","FirstCategoryId":"1085","ListUrlMain":"https://www.sciencedirect.com/science/article/pii/S0976120913000302","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
A simple and efficient stereoselective total synthesis of (−)-sedridine
An asymmetric synthesis of the piperidine alkaloid (−)-sedridine isolated from Sedum acre, has been accomplished starting from S-malic acid as the chiral precursor employing Maruoka Keck allylation, azide nucleophillic substitution and ring closing metathesis as the key steps.
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