{"title":"异金属1D配位聚合物{[CuLZn·CuLZn(H 2 O)]·H 2 O} n 的合成、表征、性质及晶体结构","authors":"陶偌偈, 李付安, 臧双全, 程延祥, 牛景杨","doi":"10.1360/ZB2006-36-1-47","DOIUrl":null,"url":null,"abstract":"合成了铜锌异金属一维链状配位聚合物, 并通过IR谱、元素分析、热分析的方法对其进行了表征和性质研究, 利用X射线单晶衍射方法对晶体结构进行了测定. 该化合物为具有{[CuLZn·CuLZn(H 2 O)]·H 2 O} n 化学组成的一维链状配位聚合物(H 4 L=N-(3-羧基水杨醛)-N′-(2-羟基苯甲酰基)乙撑二胺), 其结构单元为由两个不对称四核单元组成的两种不同的四核环, 这两种环由羧基桥联形成了1D链状配位聚合物.","PeriodicalId":49128,"journal":{"name":"Science in China. Series B, Chemistry","volume":"759 1","pages":"47-52"},"PeriodicalIF":0.0000,"publicationDate":"2006-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"异金属1D配位聚合物{[CuLZn·CuLZn(H 2 O)]·H 2 O} n 的合成、表征、性质及晶体结构\",\"authors\":\"陶偌偈, 李付安, 臧双全, 程延祥, 牛景杨\",\"doi\":\"10.1360/ZB2006-36-1-47\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"合成了铜锌异金属一维链状配位聚合物, 并通过IR谱、元素分析、热分析的方法对其进行了表征和性质研究, 利用X射线单晶衍射方法对晶体结构进行了测定. 该化合物为具有{[CuLZn·CuLZn(H 2 O)]·H 2 O} n 化学组成的一维链状配位聚合物(H 4 L=N-(3-羧基水杨醛)-N′-(2-羟基苯甲酰基)乙撑二胺), 其结构单元为由两个不对称四核单元组成的两种不同的四核环, 这两种环由羧基桥联形成了1D链状配位聚合物.\",\"PeriodicalId\":49128,\"journal\":{\"name\":\"Science in China. Series B, Chemistry\",\"volume\":\"759 1\",\"pages\":\"47-52\"},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2006-02-20\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Science in China. Series B, Chemistry\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1360/ZB2006-36-1-47\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Science in China. Series B, Chemistry","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1360/ZB2006-36-1-47","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0