{"title":"UV -颗粒活性炭催化臭氧氧化技术在去除废水中苯酚、COD和1,1,2,2-四氯乙烷中的应用","authors":"Ferry Ikhsandy, S. Bismo, E. F. Karamah","doi":"10.33366/rekabuana.v7i1.2854","DOIUrl":null,"url":null,"abstract":"Process eliminating compounds of phenol, Chemical Oxygen Demand (COD), and 1,1,2,2-tetrachloroethane using catalytic ozonation technique with catalyst Granular Activated Carbon (GAC) combination with Ultra Violet (UV) light emission performed in this study. This study aimed to obtain the effectiveness of applications catalytic ozonation technique using system configuration Ozone/GAC and Ozone/UV/GAC to eliminate waste phenol 1,1,2,2-tetrachloroethane COD with circulation time (0, 15, 30, 45, 60, and 120 minutes). The wastewater was derived from the wastewater Laboratory of Polyester Industrial in Bogor. The results were analyzed, comprised of COD with Ferrous Ammonium Sulphate (FAS) method, phenol using aminoantipirin method, and 1,1,2,2-tetrachloroethane with Gas Chromatography-Flame Ionization Detector (GC-FID) method. The result of study shown that the configuration of the Ozone/ UV/GAC with an initial concentration of phenol 58,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 32,96 mg/L resulted in the percentage of eliminating phenol 57,76%, COD 66,67% and 1,1,2,2-tetrachloroethane 98,74% while the configuration of Ozone/GAC with an initial concentration of phenol 55,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 37,70 mg/L resulted in percentage of eliminating phenol 50,91%, COD 55,56% and 1,1,2,2-tetrachloroethane 100%ABSTRAKProses penyisihan senyawa fenol, Chemical Oxygen Demand (COD) dan 1,1,2,2-tetrakloroetana menggunakan teknik ozonasi katalitik dengan katalis Granular Activated Carbon (GAC) yang dikombinasikan dengan emisi sinar Ultra Violet (UV) dilakukan dalam penelitian ini. Tujuan dari penelitian ini untuk memperoleh efektivitas aplikasi teknik ozonasi katalitik menggunakan sistem konfigurasi, yaitu: Ozon/GAC dan Ozon/UV/GAC dalam penyisihan limbah fenol, COD dan 1,1,2,2-tetrakloroetana dengan waktu sirkulasi (0, 15, 30, 45, 60, dan 120 menit). Limbah cair yang digunakan berasal dari limbah cair Laboratorium Industri Polyester di daerah Bogor. Analisis yang dilakukan meliputi analisis COD dengan metode Ferro Ammonium Sulfat (FAS), analisis Fenol dengan menggunakan metode aminoantipirin dan analisis 1,1,2,2-tetrakloroetana dengan metode Gas Chromatography-Flame Ionization Detector (GC-FID). Setelah dilakukan penelitian, diketahui bahwa konfigurasi Ozon/UV/GAC dengan konsentrasi awal fenol 58,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 32,96 mg/L menghasilkan persentase penyisihan senyawa fenol 57,76%, COD 66,67% dan 1,1,2,2-tetrakloroetana 98,74% sedangkan konfigurasi Ozon/GAC dengan konsentrasi awal fenol 55,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 37,70 mg/L menghasilkan persentase penyisihan senyawa fenol 50,91%, COD 55,56% dan 1,1,2,2-tetrakloroetana 100%.","PeriodicalId":20973,"journal":{"name":"Reka Buana : Jurnal Ilmiah Teknik Sipil dan Teknik Kimia","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2022-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"The Application of Catalytic Ozonation Technique using UV and Granular Activated Carbon (GAC) for Eliminating in Waste Phenol, COD, and 1,1,2,2-Tetrachloroethane\",\"authors\":\"Ferry Ikhsandy, S. Bismo, E. F. Karamah\",\"doi\":\"10.33366/rekabuana.v7i1.2854\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"Process eliminating compounds of phenol, Chemical Oxygen Demand (COD), and 1,1,2,2-tetrachloroethane using catalytic ozonation technique with catalyst Granular Activated Carbon (GAC) combination with Ultra Violet (UV) light emission performed in this study. This study aimed to obtain the effectiveness of applications catalytic ozonation technique using system configuration Ozone/GAC and Ozone/UV/GAC to eliminate waste phenol 1,1,2,2-tetrachloroethane COD with circulation time (0, 15, 30, 45, 60, and 120 minutes). The wastewater was derived from the wastewater Laboratory of Polyester Industrial in Bogor. The results were analyzed, comprised of COD with Ferrous Ammonium Sulphate (FAS) method, phenol using aminoantipirin method, and 1,1,2,2-tetrachloroethane with Gas Chromatography-Flame Ionization Detector (GC-FID) method. The result of study shown that the configuration of the Ozone/ UV/GAC with an initial concentration of phenol 58,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 32,96 mg/L resulted in the percentage of eliminating phenol 57,76%, COD 66,67% and 1,1,2,2-tetrachloroethane 98,74% while the configuration of Ozone/GAC with an initial concentration of phenol 55,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 37,70 mg/L resulted in percentage of eliminating phenol 50,91%, COD 55,56% and 1,1,2,2-tetrachloroethane 100%ABSTRAKProses penyisihan senyawa fenol, Chemical Oxygen Demand (COD) dan 1,1,2,2-tetrakloroetana menggunakan teknik ozonasi katalitik dengan katalis Granular Activated Carbon (GAC) yang dikombinasikan dengan emisi sinar Ultra Violet (UV) dilakukan dalam penelitian ini. Tujuan dari penelitian ini untuk memperoleh efektivitas aplikasi teknik ozonasi katalitik menggunakan sistem konfigurasi, yaitu: Ozon/GAC dan Ozon/UV/GAC dalam penyisihan limbah fenol, COD dan 1,1,2,2-tetrakloroetana dengan waktu sirkulasi (0, 15, 30, 45, 60, dan 120 menit). Limbah cair yang digunakan berasal dari limbah cair Laboratorium Industri Polyester di daerah Bogor. Analisis yang dilakukan meliputi analisis COD dengan metode Ferro Ammonium Sulfat (FAS), analisis Fenol dengan menggunakan metode aminoantipirin dan analisis 1,1,2,2-tetrakloroetana dengan metode Gas Chromatography-Flame Ionization Detector (GC-FID). Setelah dilakukan penelitian, diketahui bahwa konfigurasi Ozon/UV/GAC dengan konsentrasi awal fenol 58,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 32,96 mg/L menghasilkan persentase penyisihan senyawa fenol 57,76%, COD 66,67% dan 1,1,2,2-tetrakloroetana 98,74% sedangkan konfigurasi Ozon/GAC dengan konsentrasi awal fenol 55,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 37,70 mg/L menghasilkan persentase penyisihan senyawa fenol 50,91%, COD 55,56% dan 1,1,2,2-tetrakloroetana 100%.\",\"PeriodicalId\":20973,\"journal\":{\"name\":\"Reka Buana : Jurnal Ilmiah Teknik Sipil dan Teknik Kimia\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2022-03-28\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Reka Buana : Jurnal Ilmiah Teknik Sipil dan Teknik Kimia\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.33366/rekabuana.v7i1.2854\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Reka Buana : Jurnal Ilmiah Teknik Sipil dan Teknik Kimia","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.33366/rekabuana.v7i1.2854","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0
摘要
采用颗粒活性炭(GAC)催化臭氧化技术对苯酚、化学需氧量(COD)和1,1,2,2-四氯乙烷进行了去除。本研究旨在考察臭氧/GAC和臭氧/UV/GAC两种系统配置对循环时间分别为0、15、30、45、60和120分钟的废苯酚1,1,2,2-四氯乙烷COD的去除效果。废水来源于茂物聚酯工业废水实验室。采用硫酸亚铁铵法(FAS)分析COD，氨基安替匹林法(aminoantipirin)分析苯酚，气相色谱-火焰离子化检测器(GC-FID)分析1,1,2,2-四氯乙烷。研究结果表明，臭氧/ UV/GAC初始浓度为苯酚58 000 mg/L, COD 72 000 mg/L, 1,1,2,2-四氯乙烷32,96 mg/L时，苯酚去除率为57.76%，COD 66、67%，1,1,2,2-四氯乙烷去除率为98.74%;臭氧/GAC初始浓度为苯酚55 000 mg/L, COD 72、000 mg/L, 1,1,2,2-四氯乙烷37、70 mg/L时，苯酚去除率为50.91%。摘要:研究了紫外光对紫外光对紫外光对紫外光对紫外光对紫外光对紫外光对紫外光对紫外光对紫外光对紫外光的影响。图1:臭氧/GAC /臭氧/UV/GAC dalam penyisihan limbbaol, COD - 1,1,2,2-四氯乙烷- dengana dengan waktu sirkulasi (0,15,30,45,60, dan 120)。Limbah cair yang digunakan berasal dari Limbah cair Laboratorium industrial i Polyester di daerah Bogor。分析阳地拉坎meliputi分析COD法硫酸铁铵法(FAS)，分析Fenol法登甘孟古纳坎法氨基安替比林法分析1,1,2,2-四氯乙烷法登甘法气相色谱-火焰离子化检测器(GC-FID)。Setelah dilakukan penelitian, diketahui bahwa konsentrasi Ozon/UV/GAC登干konsentrasi awal fenol 58,00mg /L, COD 72,00mg /L, 1,1,2,2-四氯乙烷32,96 mg/L, menghasilkan代表酶penyisihan senyawa fenol 57,76%， COD 66,67%， 1,1,2,2-四氯乙烷98,74,sedangkan konsentrasi Ozon/GAC登干konsentrasi awal fenol 55,00mg /L, COD 72,00mg /L, 1,1,2,2-四氯乙烷37,70 mg/L, menghasilkan代表酶penyisihan senyawa fenol 50,91%， COD 55,56%， 1,1,2,2-四氯乙烷100%。
The Application of Catalytic Ozonation Technique using UV and Granular Activated Carbon (GAC) for Eliminating in Waste Phenol, COD, and 1,1,2,2-Tetrachloroethane
Process eliminating compounds of phenol, Chemical Oxygen Demand (COD), and 1,1,2,2-tetrachloroethane using catalytic ozonation technique with catalyst Granular Activated Carbon (GAC) combination with Ultra Violet (UV) light emission performed in this study. This study aimed to obtain the effectiveness of applications catalytic ozonation technique using system configuration Ozone/GAC and Ozone/UV/GAC to eliminate waste phenol 1,1,2,2-tetrachloroethane COD with circulation time (0, 15, 30, 45, 60, and 120 minutes). The wastewater was derived from the wastewater Laboratory of Polyester Industrial in Bogor. The results were analyzed, comprised of COD with Ferrous Ammonium Sulphate (FAS) method, phenol using aminoantipirin method, and 1,1,2,2-tetrachloroethane with Gas Chromatography-Flame Ionization Detector (GC-FID) method. The result of study shown that the configuration of the Ozone/ UV/GAC with an initial concentration of phenol 58,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 32,96 mg/L resulted in the percentage of eliminating phenol 57,76%, COD 66,67% and 1,1,2,2-tetrachloroethane 98,74% while the configuration of Ozone/GAC with an initial concentration of phenol 55,00 mg/L, COD 72,00 mg/L and 1,1,2,2-tetrachloroethane 37,70 mg/L resulted in percentage of eliminating phenol 50,91%, COD 55,56% and 1,1,2,2-tetrachloroethane 100%ABSTRAKProses penyisihan senyawa fenol, Chemical Oxygen Demand (COD) dan 1,1,2,2-tetrakloroetana menggunakan teknik ozonasi katalitik dengan katalis Granular Activated Carbon (GAC) yang dikombinasikan dengan emisi sinar Ultra Violet (UV) dilakukan dalam penelitian ini. Tujuan dari penelitian ini untuk memperoleh efektivitas aplikasi teknik ozonasi katalitik menggunakan sistem konfigurasi, yaitu: Ozon/GAC dan Ozon/UV/GAC dalam penyisihan limbah fenol, COD dan 1,1,2,2-tetrakloroetana dengan waktu sirkulasi (0, 15, 30, 45, 60, dan 120 menit). Limbah cair yang digunakan berasal dari limbah cair Laboratorium Industri Polyester di daerah Bogor. Analisis yang dilakukan meliputi analisis COD dengan metode Ferro Ammonium Sulfat (FAS), analisis Fenol dengan menggunakan metode aminoantipirin dan analisis 1,1,2,2-tetrakloroetana dengan metode Gas Chromatography-Flame Ionization Detector (GC-FID). Setelah dilakukan penelitian, diketahui bahwa konfigurasi Ozon/UV/GAC dengan konsentrasi awal fenol 58,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 32,96 mg/L menghasilkan persentase penyisihan senyawa fenol 57,76%, COD 66,67% dan 1,1,2,2-tetrakloroetana 98,74% sedangkan konfigurasi Ozon/GAC dengan konsentrasi awal fenol 55,00 mg/L, COD 72,00 mg/L dan 1,1,2,2-tetrakloroetana 37,70 mg/L menghasilkan persentase penyisihan senyawa fenol 50,91%, COD 55,56% dan 1,1,2,2-tetrakloroetana 100%.
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