基于混合有机配体的二维铜(II)配合物的合成和晶体结构

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry Pub Date : 2013-05-13 DOI:10.1080/15533174.2012.760596

Chen Fengying, W. Shumin, L. Ping, Jing Zhenguo, Zhou Chunsheng

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引用次数: 1

摘要

合成了一种新型铜(II)三元配合物，分子式为[Cu (HL) (Py) (H2O)] (H3L˭N-(2-丙酸)-水杨酰腙，Py =吡啶)，并用元素分析和x射线单晶衍射对其进行了表征。配合物中的Cu原子由HL的1个N、2个O原子和吡啶的1个N原子5个配位，这4个配位原子位于正方形金字塔的底部，另一个配位原子是H2O的O原子，位于顶端位置。分子间氢键连接络合物形成二维超级分子网络。

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Synthesis, Crystal Structure of a 2-D Copper (II) Complex Based on Mixed Organic Ligands

A novel copper (II) ternary complex with the formula [Cu (HL) (Py) (H2O)] (H3L˭N-(2-Propionic Acid)-salicyloyl hydrazone, Py = pyridine) has been synthesized and characterized by elemental analysis and single-crystal X-ray diffraction. The Cu atom in the complex is five-coordinated by one N and two O atoms of HL and one N atom from pyridine, these four atoms are located at the bottom of the square-pyramid, the other coordinating atom is O atom of H2O locating at the apical position. Intermolecular hydrogen bonds link the complex to form a 2D super molecule network.

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来源期刊

Synthesis and Reactivity in Inorganic, Metal-Organic, and Nano-Metal Chemistry 工程技术-纳米科技

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发文量

审稿时长

5 months