胶体晶体形成引起的薄膜分层的普遍性

D.T. Wasan , A.D. Nikolov , P.A. Kralchevsky , I.B. Ivanov
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引用次数: 64

摘要

实验结果与不同的胶体系统(离子和非离子胶束,膨胀胶束,乳胶悬浮液)提出,以证明称为薄膜分层现象的普遍性(逐步变薄的液体薄膜)。对这一现象提出了一种一般性的解释,假设分层是由薄膜内球形颗粒(胶束、乳胶颗粒等)形成的胶体晶体状结构逐层排出引起的。从这个角度解释了表面活性剂和电解质浓度、温度等因素对分层的影响。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Universality in film stratification due to colloid crystal formation

Experimental results with different colloidal systems (ionic and non-ionic micelles, swollen micelles, latex suspensions) are presented to demonstrate the universality of the phenomenon termed film stratification (stepwise thinning of liquid films). A general explanation of the phenomenon is proposed which assumes that the stratification is caused by the layer-by-layer expulsion of a colloid crystal-like structure formed by spherical particles (micelles, latex particles, etc.) inside the film. The effect of different factors on the stratification such as surfactant and electrolyte concentrations, temperature, etc. is explained from this viewpoint.

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